One-Pot, Three-Phase Recycling of Metals from Li-Ion Batteries in Rotating, Concentric-Liquid Reactors.
batteries
concentric-liquid reactors
lithium
recycling
Journal
Advanced materials (Deerfield Beach, Fla.)
ISSN: 1521-4095
Titre abrégé: Adv Mater
Pays: Germany
ID NLM: 9885358
Informations de publication
Date de publication:
Jul 2023
Jul 2023
Historique:
revised:
20
02
2023
received:
20
12
2022
medline:
18
3
2023
pubmed:
18
3
2023
entrez:
17
3
2023
Statut:
ppublish
Résumé
Efficient recycling of spent lithium-ion batteries (LIBs) is essential for making their numerous applications sustainable. Hydrometallurgy-based separation methods are an indispensable part of the recycling process but remain limited by the extraction efficiency and selectivity, and typically require numerous binary liquid-liquid extraction steps in which the capacity of the extracting organic phase or partition coefficient of extracted metals become an overall bottleneck. Herein, rotating reactors are described, in which the aqueous feed, organic extractant, and aqueous acceptor phases are all present in the same rotating vessel and can be vigorously stirred and emulsified without the coalescence of aqueous layers. In this arrangement, the extractant molecules are not equilibrated with the feed and, instead, "shuttle" between the feed/extractant and the extractant/acceptor interfaces multiple times, with each such molecule ultimately transferring approximately ten metal ions. This shuttling allows for using extractant concentrations much lower than in previous designs even for extremely concentrated feeds and, simultaneously, ensures unprecedented speed and selectivity of the one-pot processes. These experimental results are accompanied by theoretical considerations of the selectivity versus speed trends as well as discussion of parameters essential for system upscaling.
Identifiants
pubmed: 36929040
doi: 10.1002/adma.202211946
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2211946Subventions
Organisme : Institute for Basic Science, Korea
ID : IBS-R020-D1
Informations de copyright
© 2023 Wiley-VCH GmbH.
Références
E. Fan, L. Li, Z. Wang, J. Lin, Y. Huang, Y. Yao, R. Chen, F. Wu, Chem. Rev. 2020, 120, 7020.
Y. Huang, C. Bauer, S. Burkhardt, N. P. Dasgupta, L. A.-W. Ellingsen, L. L. Gaines, H. Hao, R. Hischier, L. Hu, Y.-M. Huang, J. Janek, C. Liang, H. Li, J. Li, Y. Li, Y.-C. Lu, W. Luo, L. F. Nazar, E. A. Olivetti, J. F. Peters, J. L. M. Rupp, M. Weil, J. F. Whitacre, S. Xu, Nat. Sustain. 2022, 5, 194.
Nature 2021, 595, 7.
C. P. Grey, D. S. Hall, Nat. Commun. 2020, 11, 6279.
T. Or, S. W. D. Gourley, K. Kaliyappan, A. Yu, Z. Chen, Carbon Energy 2020, 2, 6.
A. Manthiram, Nat. Commun. 2020, 11, 1550.
A. Accardo, G. Dotelli, M. L. Musa, E. Spessa, Appl. Sci. 2021, 11, 1160.
A. Wołos, D. Koszelewski, R. Roszak, S. Szymkuć, M. Moskal, R. Ostaszewski, B. T. Herrera, J. M. Maier, G. Brezicki, J. Samuel, J. A. M. Lummiss, D. T. McQuade, L. Rogers, B. A. Grzybowski, Nature 2022, 604, 668.
T. Keijer, V. Bakker, J. C. Slootweg, Nat. Chem. 2019, 11, 190.
N. Suchek, C. I. Fernandes, S. Kraus, M. Filser, H. Sjögrén, Bus. Strateg. Environ. 2021, 30, 3686.
G. Harper, R. Sommerville, E. Kendrick, L. Driscoll, P. Slater, R. Stolkin, A. Walton, P. Christensen, O. Heidrich, S. Lambert, A. Abbott, K. Ryder, L. Gaines, P. Anderson, Nature 2019, 575, 75.
J. Baars, T. Domenech, R. Bleischwitz, H. E. Melin, O. Heidrich, Nat. Sustain. 2021, 4, 71.
M. Chen, X. Ma, B. Chen, R. Arsenault, P. Karlson, N. Simon, Y. Wang, Joule 2019, 3, 2622.
Q. Dai, J. Spangenberger, S. Ahmed, L. Gaines, J. C. Kelly, M. Wang, EverBatt: A Closed-Loop Battery Recycling Cost and Environmental Impacts Model, Argonne, IL, USA 2019.
F. D. Castro, M. Vaccari, L. Cutaia, Crit. Rev. Environ. Sci. Technol. 2021, 52, 2060.
L. Gaines, Sustain. Mater. Technol. 2018, 17, e00068.
L. Lander, T. Cleaver, M. A. Rajaeifar, V. Nguyen-Tien, R. J. R. Elliott, O. Heidrich, E. Kendrick, J. S. Edge, G. Offer, iScience 2021, 24, 102787.
C. Xu, Q. Dai, L. Gaines, M. Hu, A. Tukker, B. Steubing, Commun. Mater. 2020, 1, 99.
L. Brückner, J. Frank, T. Elwert, Metals 2020, 10, 1107.
S. Ducoli, A. Fahimi, E. Mousa, G. Ye, S. Federici, P. Frontera, E. Bontempi, Data Brief 2022, 42, 108018.
W. Mrozik, M. A. Rajaeifar, O. Heidrich, P. Christensen, Energy Environ. Sci. 2021, 14, 6099.
J. Neumann, M. Petranikova, M. Meeus, J. D. Gamarra, R. Younesi, M. Winter, S. Nowak, Adv. Energy Mater. 2022, 12, 2102917.
A. Holzer, S. Windisch-Kern, C. Ponak, H. Raupenstrauch, Metals 2021, 11, 149.
O. Sung Kwon, I. Sohn, Resour., Conserv. Recycl. 2020, 158, 104809.
J. F. Hellmuth, N. M. DiFilippo, M. K. Jouaneh, J. Manuf. Syst. 2021, 59, 398.
W. J. Tan, C. M. M. Chin, A. Garg, L. Gao, Int. J. Energy Res. 2021, 45, 8073.
S. Baazouzi, F. P. Rist, M. Weeber, K. P. Birke, Batteries 2021, 7, 74.
A. M. Wilson, P. J. Bailey, P. A. Tasker, J. R. Turkington, R. A. Grant, J. B. Love, Chem. Soc. Rev. 2014, 43, 123.
N. B. Devi, K. C. Nathsarma, V. Chakravortty, Hydrometallurgy 2000, 54, 117.
Y. Yao, M. Zhu, Z. Zhao, B. Tong, Y. Fan, Z. Hua, ACS Sustainable Chem. Eng. 2018, 6, 13611.
Z. Liang, C. Cai, G. Peng, J. Hu, H. Hou, B. Liu, S. Liang, K. Xiao, S. Yuan, J. Yang, ACS Sustainable Chem. Eng. 2021, 9, 5750.
W. S. Chen, H. J. Ho, Metals 2018, 8, 321.
M. Amini, A. Rahbar-Kelishami, M. Alipour, O. Vahidi, J. Membr. Sci. Res. 2018, 4, 121.
P. K. Parhi, J. Chem. 2013, 2013, 618236.
N. M. Kocherginsky, Q. Yang, L. Seelam, Sep. Purif. Technol. 2007, 53, 171.
B. Swain, H. W. Shim, C. G. Lee, Korean Chem. Eng. Res. 2019, 57, 313.
G. Saik Su, N. Morad, N. Ismail, M. Rafatullah, Sep. Purif. Rev. 2020, 51, 38.
J. De Gyves, E. R. De San Miguel, Ind. Eng. Chem. Res. 1999, 38, 2182.
G. Leon, G. Martinez, L. Leon, M. A. Guzman, Physicochem. Probl. Miner. Process. 2016, 52, 77.
S. H. Chang, Desalin. Water Treat. 2016, 57, 19785.
I. Diaconu, E. Ruse, H. Y. Aboul-Enein, A. A. Bunaciu, Crit. Rev. Anal. Chem. 2016, 46, 332.
A. L. Ahmad, A. Kusumastuti, C. J. C. Derek, B. S. Ooi, Chem. Eng. J. 2011, 171, 870.
A. Kumar, A. Thakur, P. S. Panesar, Rev. Environ. Sci. Bio/Technol. 2019, 18, 153.
O. Cybulski, M. Dygas, B. Mikulak-Klucznik, M. Siek, T. Klucznik, S. Y. Choi, R. J. Mitchell, Y. I. Sobolev, B. A. Grzybowski, Nature 2020, 586, 57.
B. A. Grzybowski, Y. I. Sobolev, O. Cybulski, B. Mikulak-Klucznik, Nat. Rev. Mater. 2022, 7, 338.
X. Judez, G. G. Eshetu, C. Li, L. M. Rodriguez-Martinez, H. Zhang, M. Armand, Joule 2018, 2, 2208.
L. Mauler, X. Lou, F. Duffner, J. Leker, Energy Adv. 2022, 1, 136.
K. Kim, D. Raymond, R. Candeago, X. Su, Nat. Commun. 2021, 12, 6554.
A. Chagnes, B. Pospiech, J. Chem. Technol. Biotechnol. 2013, 88, 1191.
N. Vieceli, N. Reinhardt, C. Ekberg, M. Petranikova, Metals 2021, 11, 54.
L. Y. Wang, M. S. Lee, J. Mol. Liq. 2017, 240, 345.
K. C. Sole, J. B. Hiskey, Hydrometallurgy 1995, 37, 129.
M. Joulié, R. Laucournet, E. Billy, J. Power Sources 2014, 247, 551.
J. Murray, NS Energy 2021, https://www.nsenergybusiness.com/features/battery-metal-prices-2021/.
A. A. Nayl, M. M. Hamed, S. E. Rizk, J. Taiwan Inst. Chem. Eng. 2015, 55, 119.
P. R. Danesi, L. Reichley-Yinger, C. Cianetti, P. G. Rickert, Solvent Extr. Ion Exch. 1984, 2, 781.
I. Van de Voorde, L. Pinoy, E. Courtijn, F. Verpoort, Solvent Extr. Ion Exch. 2006, 24, 893.
J. S. Preston, Hydrometallurgy 1982, 9, 115.
B. A. Grzybowski, K. J. M. Bishop, C. J. Campbell, M. Fialkowski, S. K. Smoukov, Soft Matter 2005, 1, 114.
C.-H. Yeang, M. Szummer, in UAI'03: Proc. Nineteenth Conf. on Uncertainty in Artificial Intelligence, ACM, New York 2002, pp. 600-607.
F. Visscher, J. van der Schaaf, T. A. Nijhuis, J. C. Schouten, Chem. Eng. Res. Des. 2013, 91, 1923.
J. B. Dunn, L. Gaines, J. C. Kelly, C. James, K. G. Gallagher, Energy Environ. Sci. 2014, 8, 158.
F. Larouche, F. Tedjar, K. Amouzegar, G. Houlachi, P. Bouchard, G. P. Demopoulos, K. Zaghib, Materials 2020, 13, 801.
M. Slattery, J. Dunn, A. Kendall, Resour., Conserv. Recycl. 2021, 174, 105755.
A. C. García, M. Latifi, A. Amini, J. Chaouki, Metals 2020, 10, 1524.
V. C. Arellano Ruiz, R. Kuchi, P. K. Parhi, J.-Y. Lee, R. K. Jyothi, Sci. Rep. 2020, 10, 16911.
M. K. Jha, A. Kumari, R. Panda, J. Rajesh Kumar, K. Yoo, J. Y. Lee, Hydrometallurgy 2016, 165, 2.
L. Xu, Y. Xiao, A. van Sandwijk, Q. Xu, Y. Yang, J. Nucl. Mater. 2015, 466, 21.