Detection and quantification of zearalenone and its modified forms in enzymatically treated oat and wheat flour.
Amylolytic enzymes
MS/MS
QuEChERS
Sulfate conjugates
Zearalenol
Journal
Journal of food science and technology
ISSN: 0022-1155
Titre abrégé: J Food Sci Technol
Pays: India
ID NLM: 0056471
Informations de publication
Date de publication:
Apr 2023
Apr 2023
Historique:
revised:
04
11
2022
accepted:
29
01
2023
entrez:
20
3
2023
pubmed:
21
3
2023
medline:
21
3
2023
Statut:
ppublish
Résumé
An analytical method for the analysis of the mycotoxin zearalenone (ZEN) and its modified forms was developed. Sample preparation was performed based on a modified QuEChERS method combined with liquid chromatography coupled to a triple quadrupole mass spectrometry detection. The method was tested for linearity, precision, limits of detection and quantification and recoveries. The evaluation of the above-mentioned parameters was performed on oat flour. The method was applied to oat and wheat flours that were submitted to an amylolytic treatment (α-amylase and amyloglucosidase), similar to the one used in the cereal-based baby food production process. A decrease in β-zearalenol (β-ZEL) and β-ZEL-14-sulfate of approximately 40% after 90 min incubation was observed, the other analytes did not show any significant changes. To our knowledge, this is the first method that approaches the identification and assessment of ZEN-sulfate derivates in a cereal matrix. The online version contains supplementary material available at 10.1007/s13197-023-05683-6.
Identifiants
pubmed: 36936126
doi: 10.1007/s13197-023-05683-6
pii: 5683
pmc: PMC10020390
doi:
Types de publication
Journal Article
Langues
eng
Pagination
1367-1375Informations de copyright
© The Author(s) 2023.
Déclaration de conflit d'intérêts
Conflict of interestAuthors declare no conflict of interest.
Références
Toxins (Basel). 2021 Dec 04;13(12):
pubmed: 34941704
Toxicol Lett. 2013 Apr 26;218(3):281-92
pubmed: 23454655
Toxicon. 2019 Apr 15;162:46-56
pubmed: 30851274
Toxins (Basel). 2020 Jun 07;12(6):
pubmed: 32517357
Food Addit Contam Part A Chem Anal Control Expo Risk Assess. 2011 Aug;28(8):1098-109
pubmed: 21598136
Food Chem Toxicol. 2014 Jul;69:220-30
pubmed: 24769018
J Food Prot. 2010 Jun;73(6):1073-6
pubmed: 20537262
Toxins (Basel). 2021 May 24;13(6):
pubmed: 34073731
Food Chem. 2015 Sep 1;182:143-9
pubmed: 25842320
FEMS Microbiol Lett. 2014 Oct;359(1):124-30
pubmed: 25145804
J Chromatogr A. 2022 Aug 16;1677:463310
pubmed: 35853424
Molecules. 2018 Apr 20;23(4):
pubmed: 29677133
Toxins (Basel). 2016 Dec 06;8(12):
pubmed: 27929415
Anal Chim Acta. 2012 Dec 5;756:37-48
pubmed: 23176738
J Food Sci Technol. 2015 Feb;52(2):662-75
pubmed: 25694675
Microorganisms. 2019 Jul 21;7(7):
pubmed: 31330922
Toxins (Basel). 2017 Feb 08;9(2):
pubmed: 28208710
Food Chem Toxicol. 2007 Jan;45(1):1-18
pubmed: 17045381