Characterization of Triacylglycerol Estolide Isomers Using High-Resolution Tandem Mass Spectrometry with Nanoelectrospray Ionization.

collision-induced dissociation estolide-branching isomers glycerol sn-regioisomers high-resolution mass spectrometry higher-energy collisional dissociation ozone-induced dissociation triacylglycerol estolides

Journal

Biomolecules
ISSN: 2218-273X
Titre abrégé: Biomolecules
Pays: Switzerland
ID NLM: 101596414

Informations de publication

Date de publication:
03 03 2023
Historique:
received: 31 01 2023
revised: 27 02 2023
accepted: 01 03 2023
medline: 30 3 2023
entrez: 29 3 2023
pubmed: 30 3 2023
Statut: epublish

Résumé

Triacylglycerol estolides (TG-EST) are biologically active lipids extensively studied for their anti-inflammatory and anti-diabetic properties. In this work, eight standards of TG-EST were synthesized and systematically investigated by nanoelectrospray tandem mass spectrometry. Mass spectra of synthetic TG-EST were studied with the purpose of enabling the unambiguous identification of these lipids in biological samples. TG-EST glycerol

Identifiants

pubmed: 36979410
pii: biom13030475
doi: 10.3390/biom13030475
pmc: PMC10046810
pii:
doi:

Substances chimiques

Triglycerides 0
Glycerol PDC6A3C0OX
Lithium 9FN79X2M3F
Fatty Acids 0
Ozone 66H7ZZK23N
Sodium 9NEZ333N27
Ions 0

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

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Auteurs

Lukáš Cudlman (L)

Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, Flemingovo Náměstí 542/2, 166 00 Prague 6, Czech Republic.
Department of Analytical Chemistry, Faculty of Science, Charles University, Hlavova 2030/8, 128 43 Prague 2, Czech Republic.

Aleš Machara (A)

Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, Flemingovo Náměstí 542/2, 166 00 Prague 6, Czech Republic.

Vladimír Vrkoslav (V)

Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, Flemingovo Náměstí 542/2, 166 00 Prague 6, Czech Republic.

Miroslav Polášek (M)

J. Heyrovský Institute of Physical Chemistry of the Czech Academy of Sciences, Dolejškova 2155/3, 182 23 Prague 8, Czech Republic.

Zuzana Bosáková (Z)

Department of Analytical Chemistry, Faculty of Science, Charles University, Hlavova 2030/8, 128 43 Prague 2, Czech Republic.

Stephen J Blanksby (SJ)

School of Chemistry and Physics and the Central Analytical Research Facility, Queensland University of Technology, Brisbane, QLD 4000, Australia.

Josef Cvačka (J)

Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, Flemingovo Náměstí 542/2, 166 00 Prague 6, Czech Republic.
Department of Analytical Chemistry, Faculty of Science, Charles University, Hlavova 2030/8, 128 43 Prague 2, Czech Republic.

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