A Modular Tubular Flow System with Replaceable Photocatalyst Membranes for Scalable Coupling and Hydrogenation.
Flow Chemistry
Heterogeneous Photocatalysis
Photocatalyst Membrane
Photocatalytic Synthesis
Scaling Up
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
22 May 2023
22 May 2023
Historique:
received:
27
02
2023
medline:
30
3
2023
pubmed:
30
3
2023
entrez:
29
3
2023
Statut:
ppublish
Résumé
Heterogeneous photocatalysis is effective for the selective synthesis of value-added chemicals at lab-scale, yet falls short of requirements for mass production (low cost and user friendliness). Here we report the design and fabrication of a modular tubular flow system embedded with replaceable photocatalyst membranes for scalable photocatalytic C-C, C-N homocoupling and hydrogenation reactions, which can be operated in either circular and continuous flow mode with high performance. The photocatalyst membranes almost fully occupy the volume of the reactor, thus enabling optimal absorption of the incident light. Additionally, the porous structured photocatalyst membranes facilitate the mass transfer of the reactants to efficiently use the active sites, resulting in 0
Identifiants
pubmed: 36988035
doi: 10.1002/anie.202302979
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202302979Subventions
Organisme : National Natural Science Foundation of China
ID : 21972100
Organisme : Innovation and Entrepreneurship Talent Project of Jiangsu
ID : JSSCRC202010539
Organisme : Suzhou Municipal Science and Technology Bureau
ID : SWY2022001
Organisme : Canada Research Chairs
Informations de copyright
© 2023 Wiley-VCH GmbH.
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