Effects of Hydrophobicity Treatment of Gas Diffusion Layers on Ice Crystallization in Polymer Electrolyte Fuel Cells.

The unassisted cold-start capability of polymer electrolyte fuel cells (PEFCs) remains challenging for large-scale automotive applications. Various studies have shown that the freezing of produced water at the cathode catalyst layer (CL) and gas diffusion layer (GDL) interface blocks the oxidant gas and leads to a cold-start failure. However, the impact of GDL properties, including substrate, size, and hydrophobicity, on the freezing behavior of supercooled water is yet to be thoroughly investigated. We use differential scanning calorimetry to perform non-isothermal calorimetric measurements on untreated and waterproofed GDLs (Toray TGP-H-060, Freudenberg H23). By conducting a large number of experiments (>100) for each type of GDL, we obtained the corresponding distribution of onset freezing temperature (