Hybrid organic-inorganic nanoparticles with associated functionality for catalytic transformation of biomass substrates.


Journal

RSC advances
ISSN: 2046-2069
Titre abrégé: RSC Adv
Pays: England
ID NLM: 101581657

Informations de publication

Date de publication:
27 Mar 2023
Historique:
received: 06 03 2023
accepted: 25 03 2023
medline: 4 4 2023
entrez: 3 4 2023
pubmed: 4 4 2023
Statut: epublish

Résumé

We present the one-pot synthesis of functionalized organosilica nanoparticles to generate multi-functional hybrid catalysts. Octadecyl, alkyl-thiol and alkyl-amino moieties were used separately and in different combinations, to generate different hybrid spherical nanoparticles with tunable acidic, basic and amphiphilic properties, covalently incorporating up to three organic functional elements onto the surface of the nanoparticles. Several parameters were optimised such as the concentration of the base employed during the hydrolysis and condensation synthesis process that showed a strong influence on the particle size. The physico-chemical properties of the hybrid materials were fully characterized by XRD, elemental and thermogravimetric analysis, electron microscopy, nitrogen adsorption isotherms and

Identifiants

pubmed: 37006368
doi: 10.1039/d3ra01486j
pii: d3ra01486j
pmc: PMC10061267
doi:

Types de publication

Journal Article

Langues

eng

Pagination

10144-10156

Informations de copyright

This journal is © The Royal Society of Chemistry.

Déclaration de conflit d'intérêts

There are no conflicts to declare.

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Auteurs

Alicia Coloma (A)

Instituto de Tecnología Química, Universitat Politècnica de València, Consejo Superior de Investigaciones Científicas 46022 Valencia Spain avelty@itq.upv.es udiaz@itq.upv.es.

Alexandra Velty (A)

Instituto de Tecnología Química, Universitat Politècnica de València, Consejo Superior de Investigaciones Científicas 46022 Valencia Spain avelty@itq.upv.es udiaz@itq.upv.es.

Urbano Díaz (U)

Instituto de Tecnología Química, Universitat Politècnica de València, Consejo Superior de Investigaciones Científicas 46022 Valencia Spain avelty@itq.upv.es udiaz@itq.upv.es.

Classifications MeSH