Energy Transfer to Molecular Adsorbates by Transient Hot Electron Spillover.
electron dynamics
energy transfer
hot carriers
hot electrons
nanoplasmonics
photocatalysis
Journal
Nano letters
ISSN: 1530-6992
Titre abrégé: Nano Lett
Pays: United States
ID NLM: 101088070
Informations de publication
Date de publication:
12 Apr 2023
12 Apr 2023
Historique:
medline:
4
4
2023
pubmed:
4
4
2023
entrez:
3
4
2023
Statut:
ppublish
Résumé
Hot electron (HE) photocatalysis is one of the most intriguing fields of nanoscience, with a clear potential for technological impact. Despite much effort, the mechanisms of HE photocatalysis are not fully understood. Here we investigate a mechanism based on transient electron spillover on a molecule and subsequent energy release into vibrational modes. We use state-of-the-art real-time Time Dependent Density Functional Theory (rt-TDDFT), simulating the dynamics of a HE moving within linear chains of Ag or Au atoms, on which CO, N
Identifiants
pubmed: 37010208
doi: 10.1021/acs.nanolett.3c00013
pmc: PMC10103299
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
2719-2725Références
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