Paddle-Wheel Dirhodium Complexes Bearing Bulky Carboxylate Ligands: Synthesis and Catalysis in Carbene Insertion Reactions.
Carbene
Carboxylic Acid
DFT Calculations
Rhodium
Selectivity
Journal
Chemistry, an Asian journal
ISSN: 1861-471X
Titre abrégé: Chem Asian J
Pays: Germany
ID NLM: 101294643
Informations de publication
Date de publication:
01 Jun 2023
01 Jun 2023
Historique:
revised:
05
04
2023
received:
16
03
2023
medline:
10
4
2023
pubmed:
10
4
2023
entrez:
9
4
2023
Statut:
ppublish
Résumé
Dirhodium complexes bearing bulky carboxylate ligands are synthesized and characterized. The steric bulk of carboxylate ligands could affect the reaction selectivity in Rh-catalyzed intramolecular reactions: Rh catalysts with bulky carboxylate ligands provided five-membered ring products preferentially via the insertion into a carbon-hydrogen bond. Meanwhile, six-membered ring products were obtained using conventional Rh catalysts via the insertion of a carbon-carbon double bond.
Identifiants
pubmed: 37032312
doi: 10.1002/asia.202300223
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202300223Subventions
Organisme : JSPS KAKENHI
ID : 20H02738
Informations de copyright
© 2023 Wiley-VCH GmbH.
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