Structure Transformation and Morphologic Modulation of Supramolecular Frameworks for Nanoseparation and Enzyme Loading.
2D/3D interconversion
enzyme carrier
membrane separation
multiple interactions
supramolecular framework
Journal
Advanced science (Weinheim, Baden-Wurttemberg, Germany)
ISSN: 2198-3844
Titre abrégé: Adv Sci (Weinh)
Pays: Germany
ID NLM: 101664569
Informations de publication
Date de publication:
06 2023
06 2023
Historique:
revised:
13
03
2023
received:
29
11
2022
medline:
5
6
2023
pubmed:
15
4
2023
entrez:
14
4
2023
Statut:
ppublish
Résumé
Supramolecular framework (SF) encourages the emergence of porous structures with molecular flexibility while the dimension and morphology controls are less involved even though critical factors are vital for various utilizations. Targeting this purpose, two isolated components are designed and their stepped combinations via ionic interaction, metal coordination, and hydrogen bond into framework assembly with two morphologic states are realized. The zinc coordination to an ionic complex of polyoxometalate with three cationic terpyridine ligands constructs 2D hexagonal SF structure. A further growth along perpendicular direction driven by hydrogen bonding between grafted mannose groups leads to 3D SF assemblies, providing a modulation superiority in one framework for multiple utilizations. The large area of multilayered SF sheet affords a filtration membrane for strict separation of nanoparticles/proteins under gently reduced pressures while the granular SF assembly demonstrates an efficient carrier to load and fix horse radish peroxidase with maintained activity for enzymatic catalysis.
Identifiants
pubmed: 37060107
doi: 10.1002/advs.202207047
pmc: PMC10238212
doi:
Substances chimiques
Metals
0
Zinc
J41CSQ7QDS
Types de publication
Journal Article
Research Support, Non-U.S. Gov't
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2207047Subventions
Organisme : National Natural Science Foundation of China
ID : 22271117
Organisme : National Natural Science Foundation of China
ID : 22172060
Organisme : Program for JLU Science and Technology Innovative Research Team
ID : 2017TD-10
Informations de copyright
© 2023 The Authors. Advanced Science published by Wiley-VCH GmbH.
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