Quo Vadis Carbanionic Polymerization?
Journal
ACS polymers Au
ISSN: 2694-2453
Titre abrégé: ACS Polym Au
Pays: United States
ID NLM: 9918248914506676
Informations de publication
Date de publication:
12 Apr 2023
12 Apr 2023
Historique:
received:
28
10
2022
revised:
02
12
2022
accepted:
02
12
2022
medline:
18
4
2023
entrez:
17
4
2023
pubmed:
18
4
2023
Statut:
epublish
Résumé
Living anionic polymerization will soon celebrate 70 years of existence. This living polymerization is considered the mother of all living and controlled/living polymerizations since it paved the way for their discovery. It provides methodologies for synthesizing polymers with absolute control of the essential parameters that affect polymer properties, including molecular weight, molecular weight distribution, composition and microstructure, chain-end/in-chain functionality, and architecture. This precise control of living anionic polymerization generated tremendous fundamental and industrial research activities, developing numerous important commodity and specialty polymers. In this Perspective, we present the high importance of living anionic polymerization of vinyl monomers by providing some examples of its significant achievements, presenting its current status, giving several insights into where it is going (Quo Vadis) and what the future holds for this powerful synthetic method. Furthermore, we attempt to explore its advantages and disadvantages compared to controlled/living radical polymerizations, the main competitors of living carbanionic polymerization.
Identifiants
pubmed: 37065716
doi: 10.1021/acspolymersau.2c00058
pmc: PMC10103213
doi:
Types de publication
Journal Article
Review
Langues
eng
Pagination
158-181Informations de copyright
© 2022 The Authors. Published by American Chemical Society.
Déclaration de conflit d'intérêts
The authors declare no competing financial interest.
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