Relation between oxidation kinetics and reactant transport in an aqueous foam.

Advection Aqueous foams Diffusion Leaching Oxidation kinetics

Journal

Journal of colloid and interface science
ISSN: 1095-7103
Titre abrégé: J Colloid Interface Sci
Pays: United States
ID NLM: 0043125

Informations de publication

Date de publication:
Aug 2023
Historique:
received: 20 01 2023
revised: 17 03 2023
accepted: 22 03 2023
medline: 18 4 2023
pubmed: 18 4 2023
entrez: 17 4 2023
Statut: ppublish

Résumé

Aqueous foams are expected to constitute exquisite particularly suitable reactive medium for the oxidation of metals, since the reactant H To test this hypothesis, we investigated the oxidation of a metallic copper cylinder immersed in an aqueous foam. To study the relation between the transport of these reactants and the kinetics of the chemical reaction we use a forced drainage setup which enables us to control both the advection velocity of the H We find experimentally that the mass of dissolved copper presents a maximum with the drainage flow rate, and thus with the foam liquid fraction. Modeling analytically the transfer of H

Identifiants

pubmed: 37068360
pii: S0021-9797(23)00505-2
doi: 10.1016/j.jcis.2023.03.140
pii:
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

267-275

Informations de copyright

Copyright © 2023 Elsevier Inc. All rights reserved.

Déclaration de conflit d'intérêts

Declaration of Competing Interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: Monteux reports was provided by French National Research Agency.

Auteurs

Pierre Trinh (P)

Soft Matter Science and Engineering, CNRS, ESPCI, PSL University, Sorbonne University, 10 rue Vauquelin, 75005 Paris, France.

Alesya Mikhailovskaya (A)

Soft Matter Science and Engineering, CNRS, ESPCI, PSL University, Sorbonne University, 10 rue Vauquelin, 75005 Paris, France.

Grégory Lefèvre (G)

Chimie ParisTech, PSL Research University, CNRS, Institut de Recherche de Chimie Paris (IRCP), F-75005 Paris, France.

Nadège Pantoustier (N)

Soft Matter Science and Engineering, CNRS, ESPCI, PSL University, Sorbonne University, 10 rue Vauquelin, 75005 Paris, France.

Patrick Perrin (P)

Soft Matter Science and Engineering, CNRS, ESPCI, PSL University, Sorbonne University, 10 rue Vauquelin, 75005 Paris, France.

Elise Lorenceau (E)

Univ. Grenoble Alpes, CNRS, LIPhy, 38000 Grenoble, France.

Benjamin Dollet (B)

Univ. Grenoble Alpes, CNRS, LIPhy, 38000 Grenoble, France.

Cécile Monteux (C)

Soft Matter Science and Engineering, CNRS, ESPCI, PSL University, Sorbonne University, 10 rue Vauquelin, 75005 Paris, France.

Classifications MeSH