Bromobenzene Transforms Lanthanoid Pseudo-Grignard Chemistry.

Pseudo-Grignard reagents bromine-bridge dimers crystal structures europium lanthanoid(II) complexes oxidative addition samarium ytterbium

Journal

Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783

Informations de publication

Date de publication:
27 Jun 2023
Historique:
received: 27 03 2023
medline: 19 4 2023
pubmed: 19 4 2023
entrez: 18 04 2023
Statut: ppublish

Résumé

Divalent lanthanoid pseudo-Grignard reagents PhLnBr (Ln=Sm, Eu and Yb) can be easily prepared by the oxidative addition of bromobenzene (PhBr) to lanthanoid metals in tetrahydrofuran (THF). PhLnBr reacts with bulky N,N'-bis(2,6-di-isopropylphenyl)formamidine (DippFormH) to generate Ln

Identifiants

pubmed: 37072374
doi: 10.1002/chem.202300956
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e202300956

Subventions

Organisme : Australian Research Council
ID : DP230100112

Informations de copyright

© 2023 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH.

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Auteurs

Md Abdul Halim (MA)

College of Science & Engineering, James Cook University, Townsville, 4811, Qld, Australia.

Zhifang Guo (Z)

College of Science & Engineering, James Cook University, Townsville, 4811, Qld, Australia.

Glen B Deacon (GB)

School of Chemistry, Monash University, Clayton, 3800, Australia.

Peter C Junk (PC)

College of Science & Engineering, James Cook University, Townsville, 4811, Qld, Australia.

Classifications MeSH