Supramolecular temperature responsive assembly of polydopamine reduced graphene oxide.

Graphene oxide (GO) and reduced graphene oxide (rGO) colloidal systems can directly respond to environmental stimuli such as pH, ionic strength, and light by themselves, but not to temperature. Here we show that surface modification of rGO with polydopamine (PDA) leads to a temperature-responsive composite material, even though neither rGO nor PDA have intrinsic temperature responsiveness. Reducing GO with dopamine results in rGO/PDA flakes with hydrophilic PDA clusters attached to hydrophobic rGO domains, which mimics the amphiphilic structure of temperature responsive poly(