Entering Voltage Hysteresis in Phase-Separating Materials: Revealing the Electrochemical Signature of the Intraparticle Phase-Separated State.
batteries
intraparticle phase-separation
lithium iron phosphate
phase-separating materials
voltage hysteresis
Journal
Advanced materials (Deerfield Beach, Fla.)
ISSN: 1521-4095
Titre abrégé: Adv Mater
Pays: Germany
ID NLM: 9885358
Informations de publication
Date de publication:
Aug 2023
Aug 2023
Historique:
revised:
24
04
2023
received:
23
11
2022
medline:
30
4
2023
pubmed:
30
4
2023
entrez:
30
4
2023
Statut:
ppublish
Résumé
Hysteresis is a general phenomenon regularly observed in various materials. Usually, hysteretic behavior is an intrinsic property that cannot be circumvented in the nonequilibrium operation of the system. Herein, it is shown that, at least with regard to the hysteretic behavior of phase-separating battery materials, it is possible to enter (deeply) the hysteretic loop at finite battery currents. This newly observed electric response of the electrode, which is inherent to phase-separating materials, is related to its microscopic origin arising from a (significant) share of the active material residing in an intraparticle phase-separated state. This intriguing observation is further generalized by revealing that a phase-separating material can feature (significantly) different chemical potentials at the same bulk lithiation level and temperature when exposed to the same finite current and external voltage hysteresis. Therefore, the intraparticle phase-separated state significantly affects the DC and AC characteristics of the battery. The experimental evidence for entering the intraparticle phase-separated state is supported by thermodynamic reasoning and advanced modeling. The current findings will help advance the understanding, control, diagnostics, and monitoring of batteries composed of phase-separating materials while also providing pertinent motivation for the enhancement of battery design and performance.
Identifiants
pubmed: 37120801
doi: 10.1002/adma.202210937
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2210937Subventions
Organisme : Slovenian Research Agency
ID : P2-0401
Organisme : Slovenian Research Agency
ID : P2-0393
Organisme : Slovenian Research Agency
ID : J7-8270
Organisme : Slovenian Research Agency
ID : J2-2494
Organisme : European Union's Horizon 2020 Research and Innovation Programme
ID : 769506
Informations de copyright
© 2023 The Authors. Advanced Materials published by Wiley-VCH GmbH.
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