Structure and Reactivity of a Seven-Coordinate Ruthenium Iodosylbenzene Complex.

Journal

Inorganic chemistry
ISSN: 1520-510X
Titre abrégé: Inorg Chem
Pays: United States
ID NLM: 0366543

Informations de publication

Date de publication:
22 May 2023
Historique:
medline: 5 5 2023
pubmed: 5 5 2023
entrez: 5 5 2023
Statut: ppublish

Résumé

Seven-coordinate (CN7) ruthenium-oxo species have attracted much attention as highly reactive intermediates in both organic and water oxidation. Apart from metal-oxo, other metal-oxidant adducts, such as metal-iodosylarenes, have also recently emerged as active oxidants. We reported herein the first example of a CN7 Ru-iodosylbenzene complex, [Ru

Identifiants

DOI: 10.1021/acs.inorgchem.3c00417 PMID: 37146252
pubmed: 37146252
doi: 10.1021/acs.inorgchem.3c00417
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

7772-7778

Auteurs

Yunling Pan (Y)

Institute of Intelligent Machines, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230031, P. R. China.
Anhui Province Key Laboratory of Advanced Catalytic Materials and Reaction Engineering, School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei 230009, P. R. China.

Miaomiao Zhou (M)

Department of Chemistry, City University of Hong Kong, Kowloon Tong 999077, Hong Kong, P. R. China.

Rui Wang (R)

Institute of Intelligent Machines, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230031, P. R. China.

Dan Song (D)

Institute of Intelligent Machines, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230031, P. R. China.
Anhui Province Key Laboratory of Advanced Catalytic Materials and Reaction Engineering, School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei 230009, P. R. China.

Shek-Man Yiu (SM)

Department of Chemistry, City University of Hong Kong, Kowloon Tong 999077, Hong Kong, P. R. China.

Jianhui Xie (J)

Anhui Province Key Laboratory of Advanced Catalytic Materials and Reaction Engineering, School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei 230009, P. R. China.
ORCID: 0000-0002-8917-7966

Kai-Chung Lau (KC)

Department of Chemistry, City University of Hong Kong, Kowloon Tong 999077, Hong Kong, P. R. China.
ORCID: 0000-0003-2125-6841

Tai-Chu Lau (TC)

Department of Chemistry, City University of Hong Kong, Kowloon Tong 999077, Hong Kong, P. R. China.
Research Center for Eco-environmental Engineering, Dongguan University of Technology, Dongguan 523808, P. R. China.
ORCID: 0000-0002-0867-9746

Yingying Liu (Y)

Institute of Intelligent Machines, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230031, P. R. China.
ORCID: 0000-0001-9845-1253

Classifications MeSH