A Triply [5]Helicene-Bridged (1,3,5)Cyclophane.
Aromaticity
Cyclophane
Helicene
Macrocycle
Perkin Reaction
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
10 Jul 2023
10 Jul 2023
Historique:
received:
21
03
2023
medline:
12
5
2023
pubmed:
12
5
2023
entrez:
11
5
2023
Statut:
ppublish
Résumé
A rigid propeller-shaped conjugated triple macrocycle consisting of two nearly perfectly stacked benzene rings and three linking [5]helicene moieties has been synthesized using a glyoxylic Perkin approach. Analysis of the electron delocalization in this atypical aromatic molecule revealed global aromaticity and a 78 π-electron circuit along the edge of its triple loop, to the detriment of the two 6 π-electron circuits in the two stacked benzene rings.
Identifiants
pubmed: 37169723
doi: 10.1002/anie.202304058
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202304058Subventions
Organisme : Agence Nationale de la Recherche
ID : ANR-19-CE07-0041
Informations de copyright
© 2023 Wiley-VCH GmbH.
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