Extending the π-Conjugated System in Spiro-Type Hole Transport Material Enhances the Efficiency and Stability of Perovskite Solar Modules.

Hole Transport Materials Modules Perovskite Solar Cells Stability π-Conjugated System

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
17 Jul 2023
Historique:
received: 26 03 2023
medline: 15 5 2023
pubmed: 15 5 2023
entrez: 15 5 2023
Statut: ppublish

Résumé

Hole transport materials (HTMs) are a key component of perovskite solar cells (PSCs). The small molecular 2,2',7,7'-tetrakis(N,N-di-p-methoxyphenyl)-amine-9,9'-spirobifluorene (spiro-OMeTAD, termed "Spiro") is the most successful HTM used in PSCs, but its versatility is imperfect. To improve its performance, we developed a novel spiro-type HTM (termed "DP") by substituting four anisole units on Spiro with 4-methoxybiphenyl moieties. By extending the π-conjugation of Spiro in this way, the HOMO level of the HTM matches well with the perovskite valence band, enhancing hole mobility and increasing the glass transition temperature. DP-based PSC achieves high power conversion efficiencies (PCEs) of 25.24 % for small-area (0.06 cm

Identifiants

pubmed: 37184396
doi: 10.1002/anie.202304350
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e202304350

Subventions

Organisme : the National Key R&D Program of China
ID : 2020YFB1506400
Organisme : the VALAIS ENERGY DEMONSTRATORS FUND,
Organisme : the Swiss National Science Foundation (SNF),
Organisme : the National Natural Science Foundation of China
ID : 61904053 and 62004057
Organisme : the 111 Project
ID : B16016
Organisme : the Fundamental Research Funds for the Central Universities
ID : 2020MS080

Informations de copyright

© 2023 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.

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Auteurs

Xuepeng Liu (X)

Beijing Key Laboratory of Novel Thin-Film Solar Cells, School of New Energy, North China Electric Power University, Beijing, 102206, P. R. China.

Bin Ding (B)

Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), 1015, Lausanne, Switzerland.

Mingyuan Han (M)

Beijing Key Laboratory of Novel Thin-Film Solar Cells, School of New Energy, North China Electric Power University, Beijing, 102206, P. R. China.

Zhenhai Yang (Z)

Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences (CAS), Ningbo, 315201, China.

Jianlin Chen (J)

Beijing Key Laboratory of Novel Thin-Film Solar Cells, School of New Energy, North China Electric Power University, Beijing, 102206, P. R. China.

Pengju Shi (P)

School of Engineering, Westlake University, Hangzhou, 310024, China.

Xiangying Xue (X)

Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences (CAS), Ningbo, 315201, China.

Rahim Ghadari (R)

Computational Chemistry Laboratory, Department of Organic and Biochemistry, Faculty of Chemistry, University of Tabriz, Tabriz, 5166616471, Iran.

Xianfu Zhang (X)

Beijing Key Laboratory of Novel Thin-Film Solar Cells, School of New Energy, North China Electric Power University, Beijing, 102206, P. R. China.

Rui Wang (R)

School of Engineering, Westlake University, Hangzhou, 310024, China.

Keith Brooks (K)

Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), 1015, Lausanne, Switzerland.

Li Tao (L)

School of Microelectronic & Faculty of Physics and Electronic Science, Hubei University, Wuhan, 430062, China.

Sachin Kinge (S)

Toyota Motor Europe, Toyota Motor Technical Centre, Advanced Technology Div., Hoge Wei 33, 1930, Zaventum, Belgium.

Songyuan Dai (S)

Beijing Key Laboratory of Novel Thin-Film Solar Cells, School of New Energy, North China Electric Power University, Beijing, 102206, P. R. China.

Jiang Sheng (J)

Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences (CAS), Ningbo, 315201, China.

Paul J Dyson (PJ)

Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), 1015, Lausanne, Switzerland.

Mohammad Khaja Nazeeruddin (MK)

Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), 1015, Lausanne, Switzerland.

Yong Ding (Y)

Beijing Key Laboratory of Novel Thin-Film Solar Cells, School of New Energy, North China Electric Power University, Beijing, 102206, P. R. China.
Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), 1015, Lausanne, Switzerland.

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