Dinuclear and tetranuclear group 10 metal complexes constructed from linear tetrasilane comprising both Si-H and Si-Si moieties.
Journal
Communications chemistry
ISSN: 2399-3669
Titre abrégé: Commun Chem
Pays: England
ID NLM: 101725670
Informations de publication
Date de publication:
15 May 2023
15 May 2023
Historique:
received:
25
02
2023
accepted:
02
05
2023
medline:
16
5
2023
pubmed:
16
5
2023
entrez:
15
5
2023
Statut:
epublish
Résumé
The activation of Si-H bonds and/or Si-Si bonds in organosilicon compounds by transition-metal species plays a crucial role for the production of functional organosilicon compounds. Although group-10-metal species are frequently used to activate Si-H and/or Si-Si bonds, so far, systematic investigation to clarify the preferences of these metal species with respect to the activation of Si-H and/or Si-Si bonds remain elusive. Here, we report that platinum(0) species that bear isocyanide or N-heterocyclic-carbene (NHC) ligands selectively activates the terminal Si-H bonds of the linear tetrasilane Ph
Identifiants
pubmed: 37188952
doi: 10.1038/s42004-023-00892-8
pii: 10.1038/s42004-023-00892-8
pmc: PMC10185686
doi:
Types de publication
Journal Article
Langues
eng
Pagination
93Subventions
Organisme : MEXT | Japan Science and Technology Agency (JST)
ID : JPMJPR20A9
Organisme : MEXT | Japan Society for the Promotion of Science (JSPS)
ID : 20H02751
Informations de copyright
© 2023. The Author(s).
Références
Chem Sci. 2022 Mar 15;13(14):4115-4121
pubmed: 35440996
Acc Chem Res. 2008 Feb;41(2):222-34
pubmed: 18247521
Chemistry. 2019 Mar 12;25(15):3761-3765
pubmed: 30762905
Chem Commun (Camb). 2020 Jul 28;56(60):8464-8467
pubmed: 32584334
Angew Chem Int Ed Engl. 2009;48(3):568-71
pubmed: 19072957
Nat Commun. 2013;4:2014
pubmed: 23764831
Chem Rev. 2015 Sep 9;115(17):9410-64
pubmed: 26044343
Chem Commun (Camb). 2019 Jun 11;55(46):6559-6562
pubmed: 31111837
Chem Rev. 2014 Dec 24;114(24):12024-87
pubmed: 25398045
Chem Rev. 2011 Feb 9;111(2):863-1071
pubmed: 21250634
Chem Rev. 2000 Aug 9;100(8):3221-56
pubmed: 11749319
Chem Commun (Camb). 2021 Aug 3;57(62):7649-7652
pubmed: 34254083
Chem Rev. 2017 Jul 12;117(13):8977-9015
pubmed: 28060495
Chem Soc Rev. 2004 Nov 30;33(9):610-8
pubmed: 15592626
Angew Chem Int Ed Engl. 2015 May 4;54(19):5578-82
pubmed: 25864711
J Am Chem Soc. 2019 Jan 9;141(1):626-634
pubmed: 30516372
Chem Rev. 2016 Oct 12;116(19):11291-11435
pubmed: 27533336
Angew Chem Int Ed Engl. 2011 Jun 27;50(27):6004-11
pubmed: 21648027
Chem Rev. 1999 Jan 13;99(1):175-292
pubmed: 11848982
J Am Chem Soc. 2011 Nov 23;133(46):18598-601
pubmed: 22003822
Chem Rev. 2014 Sep 10;114(17):8613-61
pubmed: 25062400
Dalton Trans. 2013 Mar 21;42(11):4052-8
pubmed: 23340919
Chem Commun (Camb). 2012 Feb 18;48(15):2125-7
pubmed: 22241522
Inorg Chem. 2021 Oct 18;60(20):15101-15105
pubmed: 34558907
Chem Sci. 2022 Jun 15;13(25):7610-7615
pubmed: 35872831
Dalton Trans. 2010 Jul 28;39(28):6434-40
pubmed: 20532269
Chemistry. 2017 Jan 26;23(6):1386-1392
pubmed: 27864855
Angew Chem Int Ed Engl. 2000 Nov 17;39(22):4053-4055
pubmed: 11093202
Angew Chem Int Ed Engl. 2015 Feb 23;54(9):2679-83
pubmed: 25641406