Aromatic C-C Bond Cleavage in a Curved π-System of Aminocorannulene.

Journal

Organic letters
ISSN: 1523-7052
Titre abrégé: Org Lett
Pays: United States
ID NLM: 100890393

Informations de publication

Date de publication:
02 Jun 2023
Historique:
medline: 19 5 2023
pubmed: 19 5 2023
entrez: 19 5 2023
Statut: ppublish

Résumé

We report a metal- and oxidant-free aromatic C-C bond cleavage in the curved corannulene skeleton. Reaction of 1-aminocorannulene with hydrazonyl chloride generates an amidrazone intermediate that undergoes facile intramolecular proton migrations and ring annulation to give a 1,2,4-triazole derivative of planar benzo[

Identifiants

DOI: 10.1021/acs.orglett.3c01107 PMID: 37204179
pubmed: 37204179
doi: 10.1021/acs.orglett.3c01107
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

3972-3977

Auteurs

Weijie Guo (W)

College of Chemistry, Beijing Normal University, Beijing 100875, China.

Wanjian Ding (W)

College of Chemistry, Beijing Normal University, Beijing 100875, China.
ORCID: 0000-0002-4970-5816

Yuqing Yao (Y)

College of Chemistry, Beijing Normal University, Beijing 100875, China.

Suchada Rajca (S)

Department of Chemistry, University of Nebraska, Lincoln, Nebraska 68588-0304, United States.

Qiaolian Li (Q)

Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.

Hua Jiang (H)

College of Chemistry, Beijing Normal University, Beijing 100875, China.
ORCID: 0000-0002-9917-2683

Andrzej Rajca (A)

Department of Chemistry, University of Nebraska, Lincoln, Nebraska 68588-0304, United States.
ORCID: 0000-0002-8856-1536

Ying Wang (Y)

College of Chemistry, Beijing Normal University, Beijing 100875, China.
ORCID: 0000-0002-7015-7228

Classifications MeSH