Optical Binding-Driven Micropatterning and Photosculpting with Silver Nanorods.
metal-enhanced luminescence
microarrays
nanoclusters
nanorods
optical trapping
photodeposition
Journal
Small methods
ISSN: 2366-9608
Titre abrégé: Small Methods
Pays: Germany
ID NLM: 101724536
Informations de publication
Date de publication:
Sep 2023
Sep 2023
Historique:
revised:
08
04
2023
received:
18
01
2023
medline:
25
5
2023
pubmed:
25
5
2023
entrez:
25
5
2023
Statut:
ppublish
Résumé
Controlling the nano- and micropatterning of metal structures is an important requirement for various technological applications in photonics and biosensing. This work presents a method for controllably creating silver micropatterns by laser-induced photosculpting. Photosculpting is driven by plasmonic interactions between pulsed laser radiation and silver nanorods (AgNRs) in aqueous suspension; this process leads to optical binding forces transporting the AgNRs in the surroundings, while electronic thermalization results in photooxidation, melting, and ripening of the AgNRs into well-defined 3D structures. This work call these structures Airy castles due to their structural similarity with a diffraction-limited Airy disk. The photosculpted Airy castles contain emissive Ag nanoclusters, allowing for the visualization and examination of the aggregation process using luminescence microscopy. This work comprehensively examines the factors that define the photosculpting process, namely, the concentration and shape of the AgNRs, as well as the energy, power, and repetition rate of the laser. Finally, this work investigates the potential applications by measuring the metal-enhanced luminescence of a europium-based luminophore using Airy castles.
Identifiants
pubmed: 37226694
doi: 10.1002/smtd.202300076
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2300076Subventions
Organisme : MCIN/AEI/10.13039/501100011033 and the European Regional Development Fund (ERDF)
ID : CTQ2017-85658-R
Organisme : MCIN/AEI/10.13039/501100011033
ID : PID2020-114256RB-I00
Organisme : European Union's Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie
ID : 101007934
Organisme : Fundação para a Ciência e a Tecnologia, I.P
ID : UIDB/00100/2020
Organisme : Fundação para a Ciência e a Tecnologia, I.P
ID : 2022.04076.PTDC
Informations de copyright
© 2023 The Authors. Small Methods published by Wiley-VCH GmbH.
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