Laser-Driven Transient Phase Oscillations in Individual Spin Crossover Particles.
Monte Carlo calculations
phase transformations
spin crossover materials
ultrafast transmission electron microscopy
Journal
Small (Weinheim an der Bergstrasse, Germany)
ISSN: 1613-6829
Titre abrégé: Small
Pays: Germany
ID NLM: 101235338
Informations de publication
Date de publication:
Sep 2023
Sep 2023
Historique:
received:
10
05
2023
medline:
29
5
2023
pubmed:
29
5
2023
entrez:
28
5
2023
Statut:
ppublish
Résumé
An unusual expansion dynamics of individual spin crossover nanoparticles is studied by ultrafast transmission electron microscopy. After exposure to nanosecond laser pulses, the particles exhibit considerable length oscillations during and after their expansion. The vibration period of 50-100 ns is of the same order of magnitude as the time that the particles need for a transition from the low-spin to the high-spin state. The observations are explained in Monte Carlo calculations using a model where elastic and thermal coupling between the molecules within a crystalline spin crossover particle govern the phase transition between the two spin states. The experimentally observed length oscillations are in agreement with the calculations, and it is shown that the system undergoes repeated transitions between the two spin states until relaxation in the high-spin state occurs due to energy dissipation. Spin crossover particles are therefore a unique system where a resonant transition between two phases occurs in a phase transformation of first order.
Identifiants
pubmed: 37246252
doi: 10.1002/smll.202303701
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2303701Subventions
Organisme : Agence Nationale de Recherche
ID : ANR-22-CE09-0033-01
Organisme : Romanian Ministry of Research, Innovation and Digitisation
Organisme : CNCS/CCDI-UEFISCDI
ID : PCE
Organisme : CNCS/CCDI-UEFISCDI
ID : 2020
Organisme : CNCS/CCDI-UEFISCDI
ID : 1946
Informations de copyright
© 2023 The Authors. Small published by Wiley-VCH GmbH.
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