Leveraging Metal Nodes in Metal-Organic Frameworks for Advanced Anodic Hydrazine Oxidation Assisted Seawater Splitting.

electronic structure hydrazine oxidation reaction hydrogen evolution reaction metal nodes metal−organic frameworks

Journal

ACS nano
ISSN: 1936-086X
Titre abrégé: ACS Nano
Pays: United States
ID NLM: 101313589

Informations de publication

Date de publication:
13 Jun 2023
Historique:
medline: 1 6 2023
pubmed: 1 6 2023
entrez: 1 6 2023
Statut: ppublish

Résumé

Metal-organic frameworks (MOFs) show great promise for electrocatalysis owing to their tunable ligand structures. However, the poor stability of MOFs impedes their practical applications. Unlike the general pathway for engineering ligands, we report herein an innovative strategy for leveraging metal nodes to improve both the catalytic activity and the stability. Our electrolysis cell with a NiRh-MOF||NiRh-MOF configuration exhibited 10 mA cm

Identifiants

DOI: 10.1021/acsnano.3c02749 PMID: 37260372
pubmed: 37260372
doi: 10.1021/acsnano.3c02749
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

10906-10917

Auteurs

Xuefei Xu (X)

School of Integrated Circuits, Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan 430074, People's Republic of China.

Hsiao-Chien Chen (HC)

Center for Reliability Science and Technologies, Chang Gung University, Taoyuan 33302, Taiwan.
Kidney Research Center, Department of Nephrology, Chang Gung Memorial Hospital, Linkou, Taoyuan 33305, Taiwan.
ORCID: 0000-0001-6222-5393

Linfeng Li (L)

School of Integrated Circuits, Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan 430074, People's Republic of China.

Muhammad Humayun (M)

School of Integrated Circuits, Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan 430074, People's Republic of China.
ORCID: 0000-0003-3504-3935

Xia Zhang (X)

School of Integrated Circuits, Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan 430074, People's Republic of China.

Huachuan Sun (H)

School of Integrated Circuits, Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan 430074, People's Republic of China.

Damien P Debecker (DP)

Institute of Condensed Matter and Nanoscience (IMCN), UCLouvain, 1348 Louvain-La-Neuve, Belgium.
ORCID: 0000-0001-6500-2996

Wenjun Zhang (W)

Center of Super-Diamond and Advanced Films (COSDAF) & Department of Materials Science and Engineering, City University of Hong Kong, 83 Tat Chee Avenue, Kowloon, Hong Kong 999077, People's Republic of China.
ORCID: 0000-0002-4497-0688

Liming Dai (L)

Australian Carbon Materials Centre (A-CMC), School of Chemical Engineering, University of New South Wales, Sydney, New South Wales 2052, Australia.
ORCID: 0000-0001-7536-160X

Chundong Wang (C)

School of Integrated Circuits, Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan 430074, People's Republic of China.
ORCID: 0000-0001-6728-0519

Classifications MeSH