A de novo evolved domain improves the cadmium detoxification capacity of limpet metallothioneins.


Journal

Scientific reports
ISSN: 2045-2322
Titre abrégé: Sci Rep
Pays: England
ID NLM: 101563288

Informations de publication

Date de publication:
01 06 2023
Historique:
received: 23 03 2023
accepted: 23 05 2023
medline: 5 6 2023
pubmed: 2 6 2023
entrez: 1 6 2023
Statut: epublish

Résumé

Metallothioneins (MTs) constitute an important family of metal binding proteins. Mollusk MTs, in particular, have been used as model systems to better understand the evolution of their metal binding features and functional adaptation. In the present study two recombinantly produced MTs, LgiMT1 and LgiMT2, and their de novo evolved γ domain, of the marine limpet Lottia gigantea, were analyzed by electronic spectroscopy and mass spectrometry. Both MT proteins, as well as their γ domains, exhibit a strong binding specificity for Cd(II), but not for Zn(II) or Cu(I). The LgiMTs' γ domain renders an M

Identifiants

pubmed: 37264073
doi: 10.1038/s41598-023-35786-1
pii: 10.1038/s41598-023-35786-1
pmc: PMC10235030
doi:

Substances chimiques

Cadmium 00BH33GNGH
Zinc J41CSQ7QDS
Metals 0
Metallothionein 9038-94-2

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

8895

Informations de copyright

© 2023. The Author(s).

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Auteurs

Mario García-Risco (M)

Departament de Química, Facultat de Ciències, Universitat Autònoma de Barcelona, 08193, Cerdanyola del Vallès, Spain.

Sara Calatayud (S)

Departament de Genètica, Facultat de Biologia, Microbiologia i Estadística and Institut de Recerca de la Biodiversitat (IRBio), Universitat de Barcelona, Av. Diagonal 643, 08028, Barcelona, Spain.

Veronika Pedrini-Martha (V)

Institute of Zoology, Center of Molecular Biosciences, University of Innsbruck, Technikerstraße 25, 6020, Innsbruck, Austria.

Ricard Albalat (R)

Departament de Genètica, Facultat de Biologia, Microbiologia i Estadística and Institut de Recerca de la Biodiversitat (IRBio), Universitat de Barcelona, Av. Diagonal 643, 08028, Barcelona, Spain.

Òscar Palacios (Ò)

Departament de Química, Facultat de Ciències, Universitat Autònoma de Barcelona, 08193, Cerdanyola del Vallès, Spain.

Mercè Capdevila (M)

Departament de Química, Facultat de Ciències, Universitat Autònoma de Barcelona, 08193, Cerdanyola del Vallès, Spain. merce.capdevila@uab.cat.

Reinhard Dallinger (R)

Institute of Zoology, Center of Molecular Biosciences, University of Innsbruck, Technikerstraße 25, 6020, Innsbruck, Austria. reinhard.dallinger@uibk.ac.at.

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Classifications MeSH