Air- and water-stable and photocatalytically active germanium-based 2D perovskites by organic spacer engineering.

computational modeling germanium perovskites hydrogen generation metal halide perovskites photocatalysis

Journal

Cell reports. Physical science
ISSN: 2666-3864
Titre abrégé: Cell Rep Phys Sci
Pays: United States
ID NLM: 101769239

Informations de publication

Date de publication:
18 Jan 2023
Historique:
received: 29 04 2022
revised: 22 11 2022
accepted: 08 12 2022
medline: 9 6 2023
pubmed: 9 6 2023
entrez: 9 6 2023
Statut: epublish

Résumé

There is increasing interest in the role of metal halide perovskites for heterogeneous catalysis. Here, we report a Ge-based 2D perovskite material that shows intrinsic water stability realized through organic cation engineering. Incorporating 4-phenylbenzilammonium (PhBz) we demonstrate, by means of extended experimental and computational results, that PhBz

Identifiants

DOI: 10.1016/j.xcrp.2022.101214 PMID: 37292086 PMC: PMC10246422
pubmed: 37292086
doi: 10.1016/j.xcrp.2022.101214
pii: S2666-3864(22)00532-X
pmc: PMC10246422
doi:

Types de publication

Journal Article

Langues

eng

Pagination

101214

Informations de copyright

© 2022 The Author(s).

Déclaration de conflit d'intérêts

The authors declare no competing interests.

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Auteurs

Lidia Romani (L)

Department of Chemistry and INSTM, University of Pavia, Via Taramelli 16, 27100 Pavia, Italy.
Tecnologie di Generazione e Materiali, Ricerca sul Sistema Energetico - RSE S.p.A., Via Rubattino 54, 20134 Milano, Italy.

Andrea Speltini (A)

Department of Chemistry and INSTM, University of Pavia, Via Taramelli 16, 27100 Pavia, Italy.

Rossella Chiara (R)

Department of Chemistry and INSTM, University of Pavia, Via Taramelli 16, 27100 Pavia, Italy.

Marta Morana (M)

Department of Chemistry and INSTM, University of Pavia, Via Taramelli 16, 27100 Pavia, Italy.

Clarissa Coccia (C)

Department of Chemistry and INSTM, University of Pavia, Via Taramelli 16, 27100 Pavia, Italy.

Costanza Tedesco (C)

Department of Chemistry and INSTM, University of Pavia, Via Taramelli 16, 27100 Pavia, Italy.

Vincenza Armenise (V)

Department of Chemistry, University of Bari "Aldo Moro," via Orabona 4, 70126 Bari, Italy.

Silvia Colella (S)

National Research Council, Institute of Nanotechnology (CNR-NANOTEC), c/o Department of Chemistry, University of Bari "Aldo Moro," via Orabona 4, 70126 Bari, Italy.

Antonella Milella (A)

Department of Chemistry, University of Bari "Aldo Moro," via Orabona 4, 70126 Bari, Italy.

Andrea Listorti (A)

Department of Chemistry, University of Bari "Aldo Moro," via Orabona 4, 70126 Bari, Italy.

Antonella Profumo (A)

Department of Chemistry and INSTM, University of Pavia, Via Taramelli 16, 27100 Pavia, Italy.

Francesco Ambrosio (F)

Dipartimento di Scienze, University of Basilicata, Viale dell'Ateno Lucano, 10, 85100 Potenza, Italy.
Department of Chemistry and Biology "A. Zambelli," University of Salerno, Via Giovanni Paolo II 132, 84084 Fisciano, Salerno, Italy.
Computational Laboratory for Hybrid/Organic Photovoltaics (CLHYO), Istituto CNR di Scienze e Tecnologie Chimiche "Giulio Natta" (CNR-SCITEC), via Elce di Sotto 8, 06123 Perugia, Italy.

Edoardo Mosconi (E)

Computational Laboratory for Hybrid/Organic Photovoltaics (CLHYO), Istituto CNR di Scienze e Tecnologie Chimiche "Giulio Natta" (CNR-SCITEC), via Elce di Sotto 8, 06123 Perugia, Italy.

Riccardo Pau (R)

Department of Physics, University of Cagliari, Cittadella Universitaria S.P. Monserrato-Sestu km 0.7, 09042 Monserrato, Italy.
Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 09747 Groningen, the Netherlands.

Federico Pitzalis (F)

Department of Physics, University of Cagliari, Cittadella Universitaria S.P. Monserrato-Sestu km 0.7, 09042 Monserrato, Italy.

Angelica Simbula (A)

Department of Physics, University of Cagliari, Cittadella Universitaria S.P. Monserrato-Sestu km 0.7, 09042 Monserrato, Italy.

Damiano Ricciarelli (D)

Unidad Académica Preparatoria, Plantel II, Universidad Autónoma de Zacatecas, Zacatecas, Zacatecas 98068, México.

Michele Saba (M)

Department of Physics, University of Cagliari, Cittadella Universitaria S.P. Monserrato-Sestu km 0.7, 09042 Monserrato, Italy.

Maria Medina-Llamas (M)

Department of Chemistry and INSTM, University of Pavia, Via Taramelli 16, 27100 Pavia, Italy.
Unidad Académica Preparatoria, Plantel II, Universidad Autónoma de Zacatecas, Zacatecas, Zacatecas 98068, México.

Filippo De Angelis (F)

Computational Laboratory for Hybrid/Organic Photovoltaics (CLHYO), Istituto CNR di Scienze e Tecnologie Chimiche "Giulio Natta" (CNR-SCITEC), via Elce di Sotto 8, 06123 Perugia, Italy.
Department of Chemistry, Biology and Biotechnology, University of Perugia, via Elce di Sotto 8, 06123 Perugia, Italy.
Department of Natural Sciences & Mathematics, College of Sciences & Human Studies, Prince Mohammad Bin Fahd University, Dhahran 34754, Saudi Arabia.

Lorenzo Malavasi (L)

Department of Chemistry and INSTM, University of Pavia, Via Taramelli 16, 27100 Pavia, Italy.

Classifications MeSH