Modulation of supramolecular chirality by stepwise axial coordination in a nano-size trizinc(ii)porphyrin trimer.
Journal
Chemical science
ISSN: 2041-6520
Titre abrégé: Chem Sci
Pays: England
ID NLM: 101545951
Informations de publication
Date de publication:
07 Jun 2023
07 Jun 2023
Historique:
received:
15
02
2023
accepted:
09
05
2023
medline:
9
6
2023
pubmed:
9
6
2023
entrez:
9
6
2023
Statut:
epublish
Résumé
Herein, we report a chiral guest's triggered spring-like contraction and extension motions coupled with unidirectional twisting in a novel flexible and 'nano-size' achiral trizinc(ii)porphyrin trimer host upon step-wise formation of 1 : 1, 1 : 2, and 1 : 4 host-guest supramolecular complexes based on the stoichiometry of the diamine guests for the first time. During these processes, porphyrin CD responses have been induced, inverted, and amplified, and reduced, respectively, in a single molecular framework due to the change in the interporphyrin interactions and helicity. Also, the sign of the CD couplets is just the opposite between
Identifiants
pubmed: 37293642
doi: 10.1039/d3sc00858d
pii: d3sc00858d
pmc: PMC10246700
doi:
Types de publication
Journal Article
Langues
eng
Pagination
6032-6038Informations de copyright
This journal is © The Royal Society of Chemistry.
Déclaration de conflit d'intérêts
The authors declare no conflicts of interest.
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