Thallium release from biochar-amended soil to runoff in laboratory experiments.

Biochar has been widely used for trace metal(loid) (TM) immobilisation in contaminated soils. However, studies on the physicochemical mobility of TMs related to biochar application are highly limited, hampering the evaluation of the immobilisation efficiency of biochar. Therefore, after confirming the ability of biochar to decrease soil Tl bioavailability, this study examined the release of Tl in dissolved and particulate forms in surface runoff and leachate from soil mixed with biochar at different dosages and grain sizes under artificially simulated rainfall and irrigation experiments. The rainfall experimental results showed that the dissolved Tl in the surface runoff decreased from 1.30 μg in the control group to 0.75 μg and 0.54 μg in the groups with 3% and 5% biochar application, respectively. With the same dosages (5%), the finer the biochar applied, the higher the immobilisation ability achieved in surface runoff and the lower the Tl amounts in the leachate, indicating that the grain size of biochar can impact Tl mobility in dissolved forms. Comparisons between rainfall and irrigation experiments indicated that raindrops disturb the soil-water surface and enhance Tl diffusion. The mass in particulate form accounted for more than 95% of lateral released Tl in surface runoff. However, biochar application did not decrease the enrichment ratio of Tl in the eroded sediments. Notably, the finest biochar group produced less mass of eroded Tl owing to the low flux of soil erosion, indicating that grain size would indirectly impact sediment-bound Tl lateral mobility. Colloidal particles should be highlighted as they carried a maximum TI of up to 38% in the rainfall leachate. Focusing on the effect of biochar application on Tl chemical- and physical mobility from the soil matrix to runoff, this study contributes the comprehensive understanding of the role of biochar in TM remediation.

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Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.