Fibrous Zr-MOF Nanozyme Aerogels with Macro-Nanoporous Structure for Enhanced Catalytic Hydrolysis of Organophosphate Toxins.
MOFs
catalytic detoxification
nanozymes
organophosphates toxins
porous aerogels
Journal
Advanced materials (Deerfield Beach, Fla.)
ISSN: 1521-4095
Titre abrégé: Adv Mater
Pays: Germany
ID NLM: 9885358
Informations de publication
Date de publication:
13 Jun 2023
13 Jun 2023
Historique:
revised:
07
06
2023
received:
31
01
2023
pubmed:
13
6
2023
medline:
13
6
2023
entrez:
13
6
2023
Statut:
aheadofprint
Résumé
Metal-organic frameworks (MOFs) with Lewis acid catalytic sites, such as zirconium-based MOFs (Zr-MOFs), comprise a growing class of phosphatase-like nanozymes that can degrade toxic organophosphate pesticides and nerve agents. Rationally engineering and shaping MOFs from as-synthesized powders into hierarchically porous monoliths is essential for their use in emerging applications, such as filters for air and water purification and personal protection gear. However, several challenges still limit the production of practical MOF composites, including the need for sophisticated reaction conditions, low MOF catalyst loadings in the resulting composites, and poor accessibility to MOF-based active sites. To overcome these limitations, a rapid synthesis method is developed to introduce Zr-MOF nanozyme coating into cellulose nanofibers, resulting in the formation of processable monolithic aerogel composites with high MOF loadings. These composites contain Zr-MOF nanozymes embedded in the structure, and hierarchical macro-micro porosity enables excellent accessibility to catalytic active sites. This multifaceted rational design strategy, including the selection of a MOF with many catalytic sites, fine-tuning the coating morphology, and the fabrication of a hierarchically structured monolithic aerogel, renders synergistic effects toward the efficient continuous hydrolytic detoxification of organophosphorus-based nerve agent simulants and pesticides from contaminated water.
Identifiants
pubmed: 37310697
doi: 10.1002/adma.202300951
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2300951Subventions
Organisme : Army Research Office
ID : W911NF1910340
Organisme : National Science Foundation
ID : 1720139
Organisme : National Science Foundation
ID : 1048773
Organisme : National Science Foundation
ID : 0521267
Organisme : National Science Foundation
ID : 1542205
Organisme : Materials Research Center of Northwestern University
Organisme : Research Grants Council of the Hong Kong SAR Government
ID : 15208420
Informations de copyright
© 2023 The Authors. Advanced Materials published by Wiley-VCH GmbH.
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