Survival of Zirconium-Based Metal-Organic Framework Crystallinity at Extreme Pressures.


Journal

Inorganic chemistry
ISSN: 1520-510X
Titre abrégé: Inorg Chem
Pays: United States
ID NLM: 0366543

Informations de publication

Date de publication:
03 Jul 2023
Historique:
medline: 16 6 2023
pubmed: 16 6 2023
entrez: 16 6 2023
Statut: ppublish

Résumé

Recent research on metal-organic frameworks (MOFs) has shown a shift from considering only the crystalline high-porosity phases to exploring their amorphous counterparts. Applying pressure to a crystalline MOF is a common method of amorphization, as MOFs contain large void spaces that can collapse, reducing the accessible surface area. This can be either a desired change or indeed an unwanted side effect of the application of pressure. In either case, understanding the MOF's pressure response is extremely important. Three such MOFs with varying pore sizes (UiO-66, MOF-808, and NU-1000) were investigated using

Identifiants

pubmed: 37326492
doi: 10.1021/acs.inorgchem.2c04428
pmc: PMC10324312
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

10092-10099

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Auteurs

Georgina P Robertson (GP)

Department of Materials Science and Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge, Cambridgeshire CB3 0FS, U.K.
Diamond Light Source Ltd., Diamond House, Harwell Science and Innovation Campus, Didcot, Oxfordshire OX11 0DE, U.K.

Sara Mosca (S)

Central Laser Facility, STFC, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot, Oxfordshire OX11 0QX, U.K.

Celia Castillo-Blas (C)

Department of Materials Science and Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge, Cambridgeshire CB3 0FS, U.K.

Florencia A Son (FA)

Department of Chemistry and International Institute of Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States.

Omar K Farha (OK)

Department of Chemistry and International Institute of Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States.

David A Keen (DA)

ISIS Facility, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot, Oxfordshire OX11 0QX, U.K.

Simone Anzellini (S)

Diamond Light Source Ltd., Diamond House, Harwell Science and Innovation Campus, Didcot, Oxfordshire OX11 0DE, U.K.

Thomas D Bennett (TD)

Department of Materials Science and Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge, Cambridgeshire CB3 0FS, U.K.

Classifications MeSH