Enyne acetogenins from Porcelia macrocarpa displayed anti-Trypanosoma cruzi activity and cause a reduction in the intracellular calcium level.


Journal

Scientific reports
ISSN: 2045-2322
Titre abrégé: Sci Rep
Pays: England
ID NLM: 101563288

Informations de publication

Date de publication:
24 06 2023
Historique:
received: 01 03 2023
accepted: 22 06 2023
medline: 26 6 2023
pubmed: 25 6 2023
entrez: 24 6 2023
Statut: epublish

Résumé

Natural products are a promising source of new compounds with a wide spectrum of pharmacological properties, including antiprotozoal activities. Chagas disease, caused by the protozoan parasite Trypanosoma cruzi, is one of several neglected tropical diseases with reduced options for treatment, which presents limitations such as toxicity and ineffectiveness in the chronic stage of the disease. Aiming to investigate the Brazilian flora for the discovery of new anti-T. cruzi compounds, the MeOH extract from Porcelia macrocarpa R.E. Fries (Annonaceae) fruit peels displayed potent activity against trypomastigotes and intracellular amastigotes and was subjected to bioactivity-guided fractionation. Using different chromatographic steps, a fraction composed of a mixture of four new chemically related acetogenins was obtained. The compounds were characterized as (2S*,3R*,4R*)-3-hydroxy-4-methyl-2-(n-octadeca-13',17'-dien-11'-inil)butanolide (1), (2S*,3R*,4R*)-3-hydroxy-4-methyl-2-(n-eicosa-13',19'-dien-11'-inil)butanolide (2), (2S*,3R*,4R*)-3-hydroxy-4-methyl-2-(n-octadec-13'-en-11'-inil)butanolide (3), and (2S*,3R*,4R*)-3-hydroxy-4-methyl-2-(n-eicosa-13'-en-11'-inil)butanolide (4) by NMR analysis and UHPLC/ESI-HRMS data. The mixture of compounds 1-4, displayed an EC

Identifiants

pubmed: 37355735
doi: 10.1038/s41598-023-37520-3
pii: 10.1038/s41598-023-37520-3
pmc: PMC10290671
doi:

Substances chimiques

Acetogenins 0
Calcium SY7Q814VUP
Trypanocidal Agents 0

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

10254

Informations de copyright

© 2023. The Author(s).

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Auteurs

Fernanda Thevenard (F)

Centre for Natural and Human Sciences, Federal University of ABC, São Paulo, Brazil.

Ivanildo A Brito (IA)

Centre for Natural and Human Sciences, Federal University of ABC, São Paulo, Brazil.

Thais A Costa-Silva (TA)

Centre for Natural and Human Sciences, Federal University of ABC, São Paulo, Brazil.
SENAI Institute of Innovation in Biotechnology, São Paulo, 01130-000, Brazil.

Andre G Tempone (AG)

Centre for Parasitology and Mycology, Instituto Adolfo Lutz, São Paulo, Brazil. andre.tempone@ial.sp.gov.br.

João Henrique G Lago (JHG)

Centre for Natural and Human Sciences, Federal University of ABC, São Paulo, Brazil. joao.lago@ufabc.edu.br.

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Classifications MeSH