Active Role of Vapor Clouds around Evaporating Sessile Droplets in Microgravity: Marangoni Jets and Electroconvection.

A benchmark microgravity experiment (dubbed "ARLES") is analyzed. It concerns evaporation of several-μL sessile droplets with a pinned millimetric circular contact line on a flat substrate into a vast calm (here nitrogen) atmosphere at nearly normal conditions. Hydrofluoroether (HFE-7100) is used as a working liquid whose appreciable volatility and heavy vapor accentuate the contrast between the micro- and normal gravity. A possibility of switching on a DC electric field (EF) of several kV/mm orthogonally to the substrate is envisaged. We here focus on the findings intimately associated with the visualization of the vapor cloud by means of interferometry and rationalized by means of extensive simulations. In particular, with different degrees of unexpectedness, we discover and explore a Marangoni jet (without EF) and electroconvection (with EF) in the gas, which would otherwise be masked by buoyancy convection. Using the same tools, we examine some malfunctions of the space experiment.