Fused Indacene Dimers.
Antiaromaticity
Aromaticity
Diradicaloid
Indacene
Polycyclic Hydrocarbon
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
18 Sep 2023
18 Sep 2023
Historique:
received:
07
04
2023
medline:
30
6
2023
pubmed:
30
6
2023
entrez:
30
6
2023
Statut:
ppublish
Résumé
Polycyclic hydrocarbons consisting of two or more directly fused antiaromatic subunits are rare due to their high reactivity. However, it is important to understand how the interactions between the antiaromatic subunits influence the electronic properties of the fused structure. Herein, we present the synthesis of two fused indacene dimer isomers: s-indaceno[2,1-a]-s-indacene (s-ID) and as-indaceno[3,2-b]-as-indacene (as-ID), containing two fused antiaromatic s-indacene or as-indacene units, respectively. Their structures were confirmed by X-ray crystallographic analysis.
Identifiants
pubmed: 37387478
doi: 10.1002/anie.202304937
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202304937Subventions
Organisme : Ministry of Education - Singapore
ID : A-8000992-00-00
Organisme : Ministry of Education - Singapore
ID : MOE-MOET2EP10120-0006
Organisme : Agency for Science, Technology and Research (A*STAR)-Singapore
ID : M21K3c0128
Informations de copyright
© 2023 Wiley-VCH GmbH.
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