Structure and Electronics of a Series of CAAC-Stabilized Diboron-Doped Acenes from 1,4-Diboranaphthalene to 6,13-Diborapentacene.
Journal
Journal of the American Chemical Society
ISSN: 1520-5126
Titre abrégé: J Am Chem Soc
Pays: United States
ID NLM: 7503056
Informations de publication
Date de publication:
12 Jul 2023
12 Jul 2023
Historique:
medline:
30
6
2023
pubmed:
30
6
2023
entrez:
30
6
2023
Statut:
ppublish
Résumé
This combined experimental and theoretical study examines the influence of acene elongation, boron atom position, and acene substitution pattern on the structure and electronics of cyclic alkyl(amino)carbene (CAAC)-stabilized diboraacenes and presents the first syntheses of neutral diboranaphthalene (DBN) and diborapentacene (DBP). Whereas 2,3-diethyl-substituted 1,4-(CAAC)
Identifiants
pubmed: 37389841
doi: 10.1021/jacs.3c05311
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM