Hydrogen Bonded Dimer of an Alcohol with the Derived Carboxylic Acid Triggering their Sorption by Nanoporous-crystalline PPO Films.

FTIR WAXD benzoic acid benzyl alcohol dimer sorption in crystalline channels

Journal

Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783

Informations de publication

Date de publication:
02 Oct 2023
Historique:
received: 05 05 2023
medline: 4 7 2023
pubmed: 4 7 2023
entrez: 4 7 2023
Statut: ppublish

Résumé

Films exhibiting nanoporous-crystalline (NC) phases of poly(2,6-dimethyl-1,4-phenylene) oxide (PPO), which are highly effective to absorb apolar organic guest molecules, are also able to absorb polar molecules (like alcohols and carboxylic acids) but only from concentrated organic solutions. NC PPO films, which do not absorb alcohols and carboxylic acids from diluted aqueous solutions, exhibits a huge uptake (even above 30 wt %) of benzyl alcohol (BAL) and benzoic acid (BA), if BA is obtained by spontaneous room temperature oxidation of BAL in aqueous solution. This phenomenon is rationalized by an easy uptake, mainly by the PPO intrahelical crystalline empty channels, of a BAL/BA 1/1 hydrogen-bonded dimer. This huge uptake of BAL/BA dimer by NC PPO films, which is also fast for films exhibiting the orientation of the crystalline helices perpendicular to the film plane (c

Identifiants

pubmed: 37401565
doi: 10.1002/chem.202301441
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e202301441

Subventions

Organisme : Ministero dell'Istruzione, dell'Università e della Ricerca

Informations de copyright

© 2023 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH.

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Auteurs

Baku Nagendra (B)

Dipartimento di Chimica e Biologia "A.Zambelli", INSTM Research Unit, Università di Salerno, Via Giovanni Paolo II 132, 84084, Fisciano, SA, Italy.

Antonietta Cozzolino (A)

Dipartimento di Chimica e Biologia "A.Zambelli", INSTM Research Unit, Università di Salerno, Via Giovanni Paolo II 132, 84084, Fisciano, SA, Italy.

Maria Rosaria Acocella (MR)

Dipartimento di Chimica e Biologia "A.Zambelli", INSTM Research Unit, Università di Salerno, Via Giovanni Paolo II 132, 84084, Fisciano, SA, Italy.

Christophe Daniel (C)

Dipartimento di Chimica e Biologia "A.Zambelli", INSTM Research Unit, Università di Salerno, Via Giovanni Paolo II 132, 84084, Fisciano, SA, Italy.

Paola Rizzo (P)

Dipartimento di Chimica e Biologia "A.Zambelli", INSTM Research Unit, Università di Salerno, Via Giovanni Paolo II 132, 84084, Fisciano, SA, Italy.

Gaetano Guerra (G)

Dipartimento di Chimica e Biologia "A.Zambelli", INSTM Research Unit, Università di Salerno, Via Giovanni Paolo II 132, 84084, Fisciano, SA, Italy.

Classifications MeSH