Portable chemical detection platform for on-site monitoring of odorant levels in natural gas.


Journal

Journal of chromatography. A
ISSN: 1873-3778
Titre abrégé: J Chromatogr A
Pays: Netherlands
ID NLM: 9318488

Informations de publication

Date de publication:
30 Aug 2023
Historique:
received: 19 04 2023
revised: 09 06 2023
accepted: 11 06 2023
medline: 9 8 2023
pubmed: 8 7 2023
entrez: 7 7 2023
Statut: ppublish

Résumé

The adequate odorization of natural gas is critical to identify gas leaks and to reduce accidents. To ensure odorization, natural gas utility companies collect samples to be processed at core facilities or a trained human technician smells a diluted natural gas sample. In this work, we report a detection platform that addresses the lack of mobile solutions capable of providing quantitative analysis of mercaptans, a class of compounds used to odorize natural gas. Detailed description of the platform hardware and software components is provided. Designed to be portable, the platform hardware facilitates extraction of mercaptans from natural gas, separation of individual mercaptan species, and quantification of odorant concentration, with results reported at point-of-sampling. The software was developed to accommodate skilled users as well as minimally trained operators. Detection and quantification of six commonly used mercaptan compounds (ethyl mercaptan, dimethyl sulfide, n-propylmercaptan, isopropyl mercaptan, tert‑butyl mercaptan, and tetrahydrothiophene) at typical odorizing concentrations of 0.1-5 ppm was performed using the device. We demonstrate the potential of this technology to ensure natural gas odorizing concentrations throughout distribution systems.

Identifiants

pubmed: 37419015
pii: S0021-9673(23)00377-1
doi: 10.1016/j.chroma.2023.464151
pii:
doi:

Substances chimiques

Natural Gas 0
Sulfhydryl Compounds 0
Sulfur Compounds 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

464151

Subventions

Organisme : BLRD VA
ID : I01 BX004965
Pays : United States
Organisme : NCATS NIH HHS
ID : U01 TR004083
Pays : United States
Organisme : NCATS NIH HHS
ID : U18 TR003795
Pays : United States
Organisme : NIH HHS
ID : UG3 OD023365
Pays : United States

Informations de copyright

Copyright © 2023 The Author(s). Published by Elsevier B.V. All rights reserved.

Déclaration de conflit d'intérêts

Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Auteurs

Stephanie Fung (S)

Department of Mechanical and Aerospace Engineering, University of California Davis, Davis, CA, USA; UC Davis Lung Center, One Shields Avenue, Davis, CA 95616, USA.

Raquel Pimentel Contreras (RP)

Department of Mechanical and Aerospace Engineering, University of California Davis, Davis, CA, USA; UC Davis Lung Center, One Shields Avenue, Davis, CA 95616, USA.

Alexander G Fung (AG)

Department of Mechanical and Aerospace Engineering, University of California Davis, Davis, CA, USA; UC Davis Lung Center, One Shields Avenue, Davis, CA 95616, USA.

Patrick Gibson (P)

Department of Mechanical and Aerospace Engineering, University of California Davis, Davis, CA, USA; UC Davis Lung Center, One Shields Avenue, Davis, CA 95616, USA.

Michael K LeVasseur (MK)

Department of Mechanical and Aerospace Engineering, University of California Davis, Davis, CA, USA; UC Davis Lung Center, One Shields Avenue, Davis, CA 95616, USA.

Mitchell M McCartney (MM)

Department of Mechanical and Aerospace Engineering, University of California Davis, Davis, CA, USA; UC Davis Lung Center, One Shields Avenue, Davis, CA 95616, USA.; VA Northern California Health Care System, 10535 Hospital Way, Mather, CA 95655, USA.

Dylan T Koch (DT)

UC Davis Lung Center, One Shields Avenue, Davis, CA 95616, USA.; Department of Electrical Engineering, University of California Davis, Davis, CA, USA.

Pranay Chakraborty (P)

Department of Mechanical and Aerospace Engineering, University of California Davis, Davis, CA, USA; UC Davis Lung Center, One Shields Avenue, Davis, CA 95616, USA.

Bradley S Chew (BS)

Department of Mechanical and Aerospace Engineering, University of California Davis, Davis, CA, USA; UC Davis Lung Center, One Shields Avenue, Davis, CA 95616, USA.

Maneeshin Y Rajapakse (MY)

Department of Mechanical and Aerospace Engineering, University of California Davis, Davis, CA, USA; UC Davis Lung Center, One Shields Avenue, Davis, CA 95616, USA.

Daniel A Chevy (DA)

UC Davis Lung Center, One Shields Avenue, Davis, CA 95616, USA.; Department of Electrical Engineering, University of California Davis, Davis, CA, USA.

Tristan L Hicks (TL)

Department of Mechanical and Aerospace Engineering, University of California Davis, Davis, CA, USA; UC Davis Lung Center, One Shields Avenue, Davis, CA 95616, USA.

Cristina E Davis (CE)

Department of Mechanical and Aerospace Engineering, University of California Davis, Davis, CA, USA; UC Davis Lung Center, One Shields Avenue, Davis, CA 95616, USA.; VA Northern California Health Care System, 10535 Hospital Way, Mather, CA 95655, USA. Electronic address: cedavis@ucdavis.edu.

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Classifications MeSH