Study of creosote transport properties in sandy and clay soils.

Creosote DNAPL residual saturation Hydraulic conductivity Porous media Retention curve

Journal

Environmental monitoring and assessment
ISSN: 1573-2959
Titre abrégé: Environ Monit Assess
Pays: Netherlands
ID NLM: 8508350

Informations de publication

Date de publication:
19 Jul 2023
Historique:
received: 21 04 2023
accepted: 03 07 2023
medline: 21 7 2023
pubmed: 19 7 2023
entrez: 18 7 2023
Statut: epublish

Résumé

Creosote is an organic pollutant formed by a complex mixture of highly toxic and carcinogenic compounds and classified as a dense non-aqueous phase liquid (DNAPL). Its migration depends on media and fluid properties that control the multiphase flow in the subsurface. Residual saturation and hydraulic conductivity are essential parameters to accurately simulate fluid displacement in porous media. This work shows the behavior of creosote in porous medium for sandy and clay soils, collected in a contaminated area in the state of São Paulo, Brazil. Creosote retention was evaluated and compared to water. The retention curve parameters were obtained based on van Genuchten and Brooks and Corey models. The hydraulic conductivities of creosote and water are presented for both soils. The results show that, in the clay soil, water was more retained than creosote, while in the sandy soil, creosote retention was higher. The hydraulic conductivity values obtained in the clay soil show a difference of two orders of magnitude between creosote and water. Although creosote is a viscous fluid, it presents considerable mobility in the clay soil, which is relevant in remediation processes. This study advances our knowledge about DNAPL behavior in clay and sand, and no other study of creosote parameters in these porous media was found. A more accurate estimate of the time required for a liquid spill to reach groundwater can then be predicted, so that appropriate actions can be taken and risk management can be carried out.

Identifiants

pubmed: 37464226
doi: 10.1007/s10661-023-11578-y
pii: 10.1007/s10661-023-11578-y
doi:

Substances chimiques

Soil 0
Clay T1FAD4SS2M
Sand 0
Creosote 8021-39-4
Soil Pollutants 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

967

Informations de copyright

© 2023. The Author(s), under exclusive licence to Springer Nature Switzerland AG.

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Auteurs

Lélia Cristina da Rocha Soares (LC)

Department of Chemical Engineering, University of Sao Paulo, São Paulo, SP, 05508-000, Brazil. lelia.cr.soares@gmail.com.

Gabriela Paupitz Mendes (GP)

Department of Chemical Engineering, University of Sao Paulo, São Paulo, SP, 05508-000, Brazil.

Rayanne Macêdo Aranha Viegas (RMA)

Department of Chemical Engineering, Federal University of Rio Grande Do Norte, Natal, RN, 59078-970, Brazil.

Alexandre Muselli Barbosa (AM)

Department of Chemical Engineering, University of Sao Paulo, São Paulo, SP, 05508-000, Brazil.
Laboratory of Waste and Contaminated Areas, Institute for Technological Research, São Paulo, SP, 05508-901, Brazil.

Nestor Kenji Yoshikawa (NK)

Laboratory of Waste and Contaminated Areas, Institute for Technological Research, São Paulo, SP, 05508-901, Brazil.

Claudio Augusto Oller do Nascimento (CAOD)

Department of Chemical Engineering, University of Sao Paulo, São Paulo, SP, 05508-000, Brazil.

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