Germylenes Exhibiting Solid-State Emissions that Extend to NIR.
germylene carboxylates
germylene pyrrolide
metallylenes
photoluminescence
solid-state emission
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
23 Oct 2023
23 Oct 2023
Historique:
received:
15
05
2023
pubmed:
24
7
2023
medline:
24
7
2023
entrez:
24
7
2023
Statut:
ppublish
Résumé
Low-valent main group compounds that fluoresce in the solid-state were previously unknown. To address this, we investigated room-temperature photoluminescence from a series of crystals of germylenes 3-8 in this article; they exhibited emissions nearly reaching the NIR. Germylene carboxylates (3-8) were synthesized by reacting dipyrromethene stabilized germylene pyrrolide (2) with carboxylic acids such as acetic acid, trifluoroacetic acid, benzoic acid, p-cyanobenzoic acid, p-nitrobenzoic acid, and acetylsalicylic acid.
Identifiants
pubmed: 37485580
doi: 10.1002/chem.202301486
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202301486Subventions
Organisme : DST SERB
ID : EMR/2017/005519, CRG/2022/005756
Informations de copyright
© 2023 Wiley-VCH GmbH.
Références
S. Nagendran, J. Shukla, P. Shukla, P. Mahawar, Comprehensive Organometallic Chemistry IV, in Organometallic Compounds of Germanium, Vol. 10, (Eds.: G. Parkin, K. Meyer, D. O'Hare), Elsevier, Kidlington, UK, 2022, pp. 92-421.
T. J. Hadlington, M. Driess, C. Jones, Chem. Soc. Rev. 2018, 47, 4176.
S. Nagendran, H. W. Roesky, Organometallics 2008, 27, 457.
O. Kühl, Coord. Chem. Rev. 2004, 248, 411.
T. J. Hadlington, M. Hermann, G. Frenking, C. Jones, J. Am. Chem. Soc. 2014, 136, 3028;
N. Sen, S. Khan, Chem. Asian J. 2021, 16, 705.
R. K. Siwatch, S. Nagendran, Chem. Eur. J. 2014, 20, 13551;
S. Pahar, G. Kundu, S. S. Sen, ACS Omega 2020, 5, 25477.
D. Sarkar, S. Dutta, C. Weetman, E. Schubert, D. Koley, S. Inoue, Chem. Eur. J. 2021, 27, 13072.
N. D. Rio, M. L. Reyes, A. Baceiredo, N. S. Merceron, D. Lutters, T. Müller, T. Kato, Angew. Chem. Int. Ed. 2017, 129, 1385.
C. K. Jha, S. Karwasara, S. Nagendran, Chem. Eur. J. 2014, 20, 10240.
P. Mahawar, M. K. Wasson, M. K. Sharma, C. K. Jha, G. Mukherjee, P. Vivekanandan, S. Nagendran, Angew. Chem. Int. Ed. 2020, 59, 21377.
S. Kobayashi, S. I. Shoda, S. Cao, S. Iwata, M. Abe, K. Yajima, K. Yagi, M. Hiraishi, J. Macromol. Sci. A 1994, 31, 1835.
S. B. Kim, P. Sinsermsuksakul, A. S. Hock, R. D. Pike, R. G. Gordon, Chem. Mater. 2014, 26, 3065.
M. J. Polking, H. Zheng, R. Ramesh, A. P. Alivisatos, J. Am. Chem. Soc. 2011, 133, 2044.
H. Gerung, T. J. Boyle, L. J. Tribby, S. D. Bunge, C. J. Brinker, S. M. Han, J. Am. Chem. Soc. 2006, 128, 5244.
M. J. Polking, J. J. Urban, D. J. Milliron, H. Zheng, E. Chan, M. A. Caldwell, S. Raoux, C. F. Kisielowski, J. W. Ager, R. Ramesh, A. P. Alivisatos, Nano Lett. 2011, 11, 1147.
X. Cheng, D. Li, Z. Zhang, H. Zhang, Y. Wang, Org. Lett. 2014, 16, 880.
J. C. Berrones-Reyes, C. C. Vidyasagar, B. M. Muñoz Flores, V. M. Jiménez-Pérez, J. Lumin. 2018, 195, 290.
S. Karwasara, M. K. Sharma, R. Tripathi, S. Nagendran, Organometallics 2013, 32, 3830.
R. K. Siwatch, S. Karwasara, M. K. Sharma, S. Mondal, G. Mukherjee, G. Rajaraman, S. Nagendran, Organometallics 2016, 35, 429.
N. N. Zemlyansky, I. V. Borisova, V. N. Khrustalev, M. Y. Antipin, Y. A. Ustynyuk, M. S. Nechaev, V. V. Lunin, Organometallics 2003, 22, 5441.
A. Jana, B. Nekoueishahraki, H. W. Roesky, C. Schulzke, Organometallics 2009, 28, 3763.
J. Kobayashi, T. Kushida, T. Kawashima, J. Am. Chem. Soc. 2009, 131, 10836.
C. G. Gianopoulos, K. Kirschbaum, M. R. Mason, Organometallics 2014, 33, 4503.
M. J. Frisch, G. W. Trucks, H. A. Schlegel, G. E. Scuseria, M. A. Robb, J. A. Cheeseman, J. A. Montgomery, T. Vreven, K. N. Kudin, J. C. Burant, J. M. Millam, S. S. Iyengar, J. Tomasi, V. Barone, M. Mennucci, M. Cossi, G. Scalmani, N. Rega, G. A. Petersson, H. Nakatsuji, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, M. Nakajima, Y. Honda, K. Kitao, H. Nakai, M. Klene, X. Li, J. E. Knox, H. P. Hratchian, J. B. Cross, V. Bakken, V. Adamo, J. Jaramillo, R. Gomperts, R. E. Stratmann, O. Yazyev, A. J. Austin, R. Cammi, C. Pomelli, J. W. Ochterski, P. Y. Ayala, K. Morokuma, J. A. Voth, P. Salvador, J. J. Dannenberg, V. G. Zakrzewski, S. Dapprich, A. D. Daniels, M. C. Strain, O. Farkas, D. A. Malick, A. D. Rabuck, K. Raghavachari, J. B. Foresman, J. V. Ortiz, Q. Cui, A. G. Baboul, G. Clifford, J. Cioslowski, B. B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I Komaromi, R. A. Martin, D. J. Fox, T. Keith, M. A. Al-Laham, C. Y. Peng, A. Nanayakkara, M. Challacombe, P. M. W. Gill, B. Johnson, W. Chen, M. W. Wong, C. Gonzalez and J. A. Pople, Gaussian-09, Gaussian, Inc., Wallingford, CT, 2004.
R. E. Stratmann, G. E. Scuseria, M. J. Frisch, J. Chem. Phys. 1998, 109, 8218.
SMART, Bruker Molecular Analysis Research Tool, Version 5.618, Bruker AXS, Madison, WI (2000).
SAINT-NT, Version 6.04; Bruker AXS, WI (2001).
SHELXTL-NT, Version 6.10, Bruker AXS, Madison, WI (2000).
Deposition Numbers 2246361 (2), 2246356 (3), 2257650 (4), 2246357 (5), 2246358 (6), 2246359 (7), and 2246360 (8) contains the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum Karlsruhe Access Structures service.