Superacid Resin-Based Heterogeneous Catalysts for the Selective Acylation of 1,2-Methylenedioxybenzene.
Aquivion
heterogenous catalysis
in-situ characterization
ion-exchange resin
propionic anhydride
Journal
ChemSusChem
ISSN: 1864-564X
Titre abrégé: ChemSusChem
Pays: Germany
ID NLM: 101319536
Informations de publication
Date de publication:
08 Nov 2023
08 Nov 2023
Historique:
revised:
21
07
2023
received:
23
06
2023
medline:
27
7
2023
pubmed:
27
7
2023
entrez:
27
7
2023
Statut:
ppublish
Résumé
In this work, we firstly report on the use of highly active and selective Aquivion superacid resins as heterogeneous catalysts for the acylation of 1,2-methylenedioxybenzene (MDB) with propionic anhydride (AP). The reaction was investigated and optimized using solvent-free conditions to selectively produce 3,4-methylenedioxypropiophenone (MDP1P), a key intermediate for the manufacture of active ingredients used in insecticide formulations with a volume of production of roughly 3000 t/y. Interestingly, Aquivion-based catalysts allows to work in mild reaction conditions (i. e. 80 °C), obtaining MDP1P yields as high as 44 % after only 1 h of reaction (selectivity 83 %). A detailed study of the AP reactivity demonstrated its tendency to promote oligomerization reactions that, as confirmed by ex-situ and in-situ FT-ATR analyses, caused the deactivation of the catalyst forming surficial carbonaceous residues. In this context, a fast oxidation of the resin surface organic residues using a diluted HNO
Identifiants
pubmed: 37499171
doi: 10.1002/cssc.202300903
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202300903Subventions
Organisme : PON Ricerca e Innovazione
ID : 1062
Organisme : Endura S.p.A.
Informations de copyright
© 2023 The Authors. ChemSusChem published by Wiley-VCH GmbH.
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