Understanding Precatalyst Activation and Speciation in Manganese-Catalyzed C-H Bond Functionalization Reactions.


Journal

Organometallics
ISSN: 0276-7333
Titre abrégé: Organometallics
Pays: United States
ID NLM: 9881295

Informations de publication

Date de publication:
24 Jul 2023
Historique:
received: 03 01 2023
medline: 28 7 2023
pubmed: 28 7 2023
entrez: 28 7 2023
Statut: epublish

Résumé

An investigation into species formed following precatalyst activation in Mn-catalyzed C-H bond functionalization reactions is reported. Time-resolved infrared spectroscopy demonstrates that light-induced CO dissociation from precatalysts [Mn(C^N)(CO)

Identifiants

pubmed: 37502314
doi: 10.1021/acs.organomet.3c00004
pmc: PMC10369674
doi:

Types de publication

Journal Article

Langues

eng

Pagination

1766-1773

Informations de copyright

© 2023 The Authors. Published by American Chemical Society.

Déclaration de conflit d'intérêts

The authors declare no competing financial interest.

Références

J Am Chem Soc. 2019 Feb 13;141(6):2316-2328
pubmed: 30698423
Chem Sci. 2022 Oct 26;13(44):13225-13230
pubmed: 36425483
Inorg Chem. 2002 Aug 26;41(17):4318-23
pubmed: 12184746
Angew Chem Int Ed Engl. 2016 Sep 26;55(40):12455-9
pubmed: 27603008
J Comput Chem. 2007 Jan 15;28(1):320-5
pubmed: 17143872
Dalton Trans. 2020 May 7;49(17):5463-5470
pubmed: 32255172
J Am Chem Soc. 2013 Jan 30;135(4):1264-7
pubmed: 23286776
Appl Spectrosc. 2010 Dec;64(12):1311-9
pubmed: 21144146
Inorg Chem. 2002 Apr 8;41(7):1717-27
pubmed: 11925162
Appl Spectrosc. 2016 Apr;70(4):645-53
pubmed: 26887988
Chemistry. 2021 Feb 24;27(12):3979-3985
pubmed: 33135818
Angew Chem Int Ed Engl. 2014 May 5;53(19):4950-3
pubmed: 24700597
Chem Sci. 2022 Jul 8;13(34):9902-9913
pubmed: 36199635
Chemistry. 2023 May 2;29(25):e202203038
pubmed: 36625067
Chem Rev. 2019 Feb 27;119(4):2453-2523
pubmed: 30376310
J Am Chem Soc. 2021 Jan 27;143(3):1356-1364
pubmed: 33428402

Auteurs

Jonathan B Eastwood (JB)

Department of Chemistry, University of York, Heslington, York YO10 5DD, United Kingdom.

L Anders Hammarback (LA)

Department of Chemistry, University of York, Heslington, York YO10 5DD, United Kingdom.

Thomas J Burden (TJ)

Department of Chemistry, University of York, Heslington, York YO10 5DD, United Kingdom.

Ian P Clark (IP)

Central Laser Facility, Research Complex at Harwell, STFC Rutherford Appleton Laboratory, Harwell Campus, Didcot, Oxfordshire OX11 0QX, United Kingdom.

Michael Towrie (M)

Central Laser Facility, Research Complex at Harwell, STFC Rutherford Appleton Laboratory, Harwell Campus, Didcot, Oxfordshire OX11 0QX, United Kingdom.

Alan Robinson (A)

Syngenta Crop Protection AG Schaffhauserstrasse, 4332 Stein, Switzerland.

Ian J S Fairlamb (IJS)

Department of Chemistry, University of York, Heslington, York YO10 5DD, United Kingdom.

Jason M Lynam (JM)

Department of Chemistry, University of York, Heslington, York YO10 5DD, United Kingdom.

Classifications MeSH