A Single-Crystal Monomer to Single-Crystal Polymer Reaction Activated by a Triplet Excimer in a Zipper Mechanism.
Crystal Structure
Diradical Character
Mechanism
Polymerization
Triplet Excimer
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
18 Sep 2023
18 Sep 2023
Historique:
received:
22
06
2023
medline:
3
8
2023
pubmed:
3
8
2023
entrez:
3
8
2023
Statut:
ppublish
Résumé
A combined experimental and theoretical study focused on the elucidation of the polymerization mechanism of the crystal monomer to crystal polymer reaction of a bisindenedione compound in the solid state. The experimental description and characterization of the polymer product have been reported elsewhere and, in this article, we address the first detailed description of the polymerization process. This reaction pathway consists of the initial formation of a triplet excimer state that relaxes to an intermolecularly bonded triplet state that is the starting point of the propagation step of the polymerization. The overall process can be visualized in the monomer starting state as an open zipper in which a cursor or slider is formed by light absorption and the whole zipper is then closed by propagation of the cursor. To this end, variable-temperature electron spin resonance (ESR), femtosecond transient absorption spectroscopy, and vibrational Raman spectroscopic data have been implemented in combination with quantum chemical calculations. The presented mechanistic insight is of great value to understand the intricacies of such an important reaction and to envisage and diversify the products produced thereof.
Identifiants
pubmed: 37533303
doi: 10.1002/anie.202308780
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202308780Subventions
Organisme : Chengdu University of Traditional Chinese Medicine State Key Laboratory Southwestern Chinese Medicine Resources
ID : SKLTCM2022014
Organisme : Guangdong Basic and Applied Basic Research Foundation
ID : 2021A1515110431
Organisme : Intelligent Terminal Key Laboratory of Sichuan Province
ID : Grant SCITLAB (No. 20013)
Organisme : the Spanish Ministry of Science and Innovation
ID : MINECO/FEDER PID2021-127127NB-I00, PID2019-110305GB-I00, PID2019-109555GB-I00 and RED2018-102815-T
Organisme : the Junta de Andalucía
ID : PROYEXCEL-0328
Organisme : Generalidad Valenciana, Spain
ID : PIBA19-0004
Organisme : the Eusko Jaurlaritza/Basque Government
ID : 2019-CIEN-000092-01
Organisme : Engineering and Physical Sciences Research Council
ID : EP/T012455 EP/L022613 EP/R042802
Informations de copyright
© 2023 Wiley-VCH GmbH.
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