Electrochemical Enhancement of Lithium-Ion Diffusion in Polypyrrole-Modified Sulfurized Polyacrylonitrile Nanotubes for Solid-to-Solid Free-Standing Lithium-Sulfur Cathodes.
charge transport
electrochemically active additives
free-standing electrodes
hollow channels
Journal
Small (Weinheim an der Bergstrasse, Germany)
ISSN: 1613-6829
Titre abrégé: Small
Pays: Germany
ID NLM: 101235338
Informations de publication
Date de publication:
Nov 2023
Nov 2023
Historique:
revised:
17
07
2023
received:
05
05
2023
medline:
7
8
2023
pubmed:
7
8
2023
entrez:
6
8
2023
Statut:
ppublish
Résumé
The energy density of lithium-sulfurized polyacrylonitrile (Li-SPAN) batteries has chronically suffered from low sulfur content. Although a free-standing electrode can significantly reduce noncapacity mass contribution, the slow bulk reaction kinetics still constrain the electrochemical performance. In this regard, a novel electrochemically active additive, polypyrrole (PPy), is introduced to construct PAN nanotubes as a sulfur carrier. This hollow channel greatly facilitates charge transport within the electrode and increases the sulfur content. Both electrochemical tests and simulations show that the SPANPPy-1% cathode possesses a larger lithium-ion diffusion coefficient and a more homogeneous phase interface than the SPAN cathode. Consequently, significantly improved capabilities and rate properties are achieved, as well as decent exportations under high-sulfur-loading or lean-electrolyte conditions. In-situ and semi-situ characterizations are further performed to demonstrate the nucleation growth of lithium sulfide and the evolution of the electrode surface structure. This type of electrochemically active additive provides a well-supported implementation of high-energy-density Li-S batteries.
Identifiants
pubmed: 37544919
doi: 10.1002/smll.202303781
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2303781Subventions
Organisme : National Natural Science Foundation of China
ID : 21978231
Organisme : National Natural Science Foundation of China
ID : 22008193
Organisme : International Science and Technology Cooperation Program of Shaanxi Province
ID : 2022KWZ-08
Organisme : Natural Science Foundation of Jiangsu Province, China
ID : SBK2020021757
Informations de copyright
© 2023 Wiley-VCH GmbH.
Références
Z.-X. Chen, M. Zhao, L.-P. Hou, X.-Q. Zhang, B.-Q. Li, J.-Q. Huang, Adv Mater 2022, 34, 2201555.
R. Deng, M. Wang, H. Yu, S. Luo, J. Li, F. Chu, B. Liu, F. Wu, Energy Environ. Mater. 2022, 5, 777.
Z. Pan, D. J. L. Brett, G. He, I. P. Parkin, Adv. Energy Mater. 2022, 12, 2103483.
Y. Chen, T. Wang, H. Tian, D. Su, Q. Zhang, G. Wang, Adv Mater 2021, 33, 2003666.
G. Zhou, H. Chen, Y. Cui, Nat. Energy 2022, 7, 312.
Y. Xiao, Y. Xiang, S. Guo, J. Wang, Y. Ouyang, D. Li, Q. Zeng, W. Gong, L. Gan, Q. Zhang, S. Huang, Energy Storage Mater. 2022, 51, 882.
Z. Liang, J. Shen, X. Xu, F. Li, J. Liu, B. Yuan, Y. Yu, M. Zhu, Adv Mater 2022, 34, 2200102.
Z. Shen, X. Jin, J. Tian, M. Li, Y. Yuan, S. Zhang, S. Fang, X. Fan, W. Xu, H. Lu, J. Lu, H. Zhang, Nat. Catal. 2022, 5, 555.
Y. Yi, H. Li, H. Chang, P. Yang, X. Tian, P. Liu, L. Qu, M. Li, B. Yang, H. Li, Chemistry 2019, 25, 8112.
M. Zhao, B.-Q. Li, H.-J. Peng, H. Yuan, J.-Y. Wei, J.-Q. Huang, Angew Chem Int Ed Engl 2020, 59, 12636.
X. Li, L. Yuan, D. Liu, J. Xiang, Z. Li, Y. Huang, Small 2022, 18, 2106970.
Y. Yi, F. Hai, J. Guo, X. Tian, S. Zheng, Z. Wu, T. Wang, M. Li, Batteries. 2023, 9, 27.
X. Zhang, H. Ma, J. Liu, J. Chen, H. Lu, Y. Huang, J. Wang, Nano Res. 2023.
M. S. Ahmed, S. Lee, M. Agostini, M.-G. Jeong, H.-G. Jung, J. Ming, Y.-K. Sun, J. Kim, J.-Y. Hwang, Adv. Sci. 2021, 8, 2101123.
H. Yang, J. Chen, J. Yang, J. Wang, Angew. Chem., Int. Ed. 2020, 59, 7306.
B. He, Z. Rao, Z. Cheng, D. Liu, D. He, J. Chen, Z. Miao, L. Yuan, Z. Li, Y. Huang, Adv. Energy Mater. 2021, 11, 2003690.
T. Wang, Q. Zhang, J. Zhong, M. Chen, H. Deng, J. Cao, L. Wang, L. Peng, J. Zhu, B. Lu, Adv. Energy Mater. 2021, 11, 2100448.
X. Wang, Y. Qian, L. Wang, H. Yang, H. Li, Y. Zhao, T. Liu, Adv. Funct. Mater. 2019, 29, 1902929.
C. F. J. Kuo, M. A. Weret, H. Y. Hung, M. C. Tsai, C. J. Huang, W. N. Su, B. J. Hwang, J. Power Sources 2019, 412, 670.
A. Abdul Razzaq, X. Yuan, Y. Chen, J. Hu, Q. Mu, Y. Ma, X. Zhao, L. Miao, J.-H. Ahn, Y. Peng, Z. Deng, J. Mater. Chem. A 2020, 8, 1298.
A. Abdul Razzaq, G. Chen, X. Zhao, X. Yuan, J. Hu, Z. Li, Y. Chen, J. Xu, R. Shah, J. Zhong, Y. Peng, Z. Deng, J. Energy Chem.. 2021, 61, 170.
H. Dong, S. Qi, L. Wang, X. Chen, Y. Xiao, Y. Wang, B. Sun, G. Wang, S. Chen, Small n/a, 2300843.
C.-X. Zhao, X.-Y. Li, M. Zhao, Z.-X. Chen, Y.-W. Song, W.-J. Chen, J.-N. Liu, B. Wang, X.-Q. Zhang, C.-M. Chen, B.-Q. Li, J.-Q. Huang, Q. Zhang, J. Am. Chem. Soc. 2021, 143, 19865.
J. Gu, C. Dong, C. Zhou, C. Shen, Y. Pi, X. Xu, Sci. China Mater. 2023, 66, 2181.
L. Huang, T. Guan, H. Su, Y. Zhong, F. Cao, Y. Zhang, X. Xia, X. Wang, N. Bao, J. Tu, Angew. Chem., Int. Ed. 2022, 61, e202212151.
G. Wen, Y. Sui, X. Zhang, J. Li, Z. Zhang, S. Zhong, S. Tang, L. Wu, J. Colloid Interface Sci. 2021, 589, 208.
Y. Zhang, X. Zhang, S. R. P. Silva, B. Ding, P. Zhang, G. Shao, Adv. Sci. 2022, 9, 2103879.
W. Chang, J. Qu, W. Li, Y. H. Liu, X. Z. Zhai, H. J. Liu, Y. Kang, Z. Z. Yu, Small 2021, 17, 2101857.
X. Zhang, G. Hu, K. Chen, L. Shen, R. Xiao, P. Tang, C. Yan, H.-M. Cheng, Z. Sun, F. Li, Energy Storage Mater. 2022, 45, 1144.
W. Wei, J. Li, D. Liu, C. Pan, P. Liu, Energy Fuels 2020, 34, 7676.
K. Wang, T. Zhao, N. Zhang, T. Feng, L. Li, F. Wu, R. Chen, Nanoscale 2021, 13, 16690.
F. Li, M. R. Kaiser, J. Ma, Z. Guo, H. Liu, J. Wang, Energy Storage Mater. 2018, 13, 312.
Y. Liu, A. K. Haridas, Y. Lee, K.-K. Cho, J.-H. Ahn, Appl. Surf. Sci. 2019, 472, 135.
S. Wang, B. Lu, D. Cheng, Z. Wu, S. Feng, M. Zhang, W. Li, Q. Miao, M. Patel, J. Feng, E. Hopkins, J. Zhou, S. Parab, B. Bhamwala, B. Liaw, Y. S. Meng, P. Liu, J. Am. Chem. Soc. 2023, 145, 9624.
R. He, Y. Li, S. Wei, H. Liu, S. Zhang, N. Han, H. Liu, X. Wang, X. Zhang, J. Alloys Compd. 2022, 919, 165838.
Z.-Q. Jin, Y.-G. Liu, W.-K. Wang, A.-B. Wang, B.-W. Hu, M. Shen, T. Gao, P.-C. Zhao, Y.-S. Yang, Energy Storage Mater. 2018, 14, 272.
Y. Hu, B. Li, X. Jiao, C. Zhang, X. Dai, J. Song, Adv. Funct. Mater. 2018, 28, 1801010.
L. Zhang, R. Wang, Z. Liu, J. Wan, S. Zhang, S. Wang, K. Hua, X. Liu, X. Zhou, X. Luo, X. Zhang, M. Cao, H. Kang, C. Zhang, Z. Guo, Adv. Mater. 2023, 35, 2210082.
W. Xue, W. Xu, W. Wang, G. Gao, L. Wang, Compos. Commun. 2022, 30, 101078.
H. Li, W. Xue, L. Wang, T. Liu, ACS Appl. Mater. Interfaces 2021, 13, 25002.
H. Liu, R. He, Y. Li, Y. Jin, H. Liu, X. Zhang, J. Electroanal. Chem. 2023, 939, 117465.
S. Wei, L. Ma, K. E. Hendrickson, Z. Tu, L. A. Archer, J. Am. Chem. Soc. 2015, 137, 12143.
Y. Yi, W. Huang, X. Tian, B. Fang, Z. Wu, S. Zheng, M. Li, H. Ma, ACS Appl. Mater. Interfaces 2021, 13, 59983.
L. Qu, P. Liu, Y. Yi, T. Wang, P. Yang, X. Tian, M. Li, B. Yang, S. Dai, ChemSusChem 2019, 12, 213.
Q. Wang, M. Zhu, G. Chen, N. Dudko, Y. Li, H. Liu, L. Shi, G. Wu, D. Zhang, Adv. Mater. 2022, 34, 2109658.
C. Wang, J. Liang, S. Hwang, X. Li, Y. Zhao, K. Adair, C. Zhao, X. Li, S. Deng, X. Lin, X. Yang, R. Li, H. Huang, L. Zhang, S. Lu, D. Su, X. Sun, Nano Energy 2020, 72, 104686.
X. Yang, A. L. Rogach, Adv. Energy Mater. 2019, 9, 1900747.
X. Chen, H. Ji, Z. Rao, L. Yuan, Y. Shen, H. Xu, Z. Li, Y. Huang, Adv. Energy Mater. 2022, 12, 2102774.