Tailoring the Weight of Surface and Intralayer Edge States to Control LUMO Energies.

LUMO energy fullerenes intermolecular interactions rolling transfer of Langmuir layers

Journal

Advanced materials (Deerfield Beach, Fla.)
ISSN: 1521-4095
Titre abrégé: Adv Mater
Pays: Germany
ID NLM: 9885358

Informations de publication

Date de publication:
Oct 2023
Historique:
revised: 27 07 2023
received: 26 05 2023
pubmed: 13 8 2023
medline: 13 8 2023
entrez: 12 8 2023
Statut: ppublish

Résumé

The energies of the frontier molecular orbitals determine the optoelectronic properties in organic films, which are crucial for their application, and strongly depend on the morphology and supramolecular structure. The impact of the latter two properties on the electronic energy levels relies primarily on nearest-neighbor interactions, which are difficult to study due to their nanoscale nature and heterogeneity. Here, an automated method is presented for fabricating thin films with a tailored ratio of surface to bulk sites and a controlled extension of domain edges, both of which are used to control nearest-neighbor interactions. This method uses a Langmuir-Schaefer-type rolling transfer of Langmuir layers (rtLL) to minimize flow during the deposition of rigid Langmuir layers composed of π-conjugated molecules. Using UV-vis absorption spectroscopy, atomic force microscopy, and transmission electron microscopy, it is shown that the rtLL method advances the deposition of multi-Langmuir layers and enables the production of films with defined morphology. The variation in nearest-neighbor interactions is thus achieved and the resulting systematically tuned lowest unoccupied molecular orbital (LUMO) energies (determined via square-wave voltammetry) enable the establishment of a model that functionally relates the LUMO energies to a morphological descriptor, allowing for the prediction of the range of accessible LUMO energies.

Identifiants

pubmed: 37572365
doi: 10.1002/adma.202305006
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e2305006

Subventions

Organisme : German Research Foundation
ID : 364549901
Organisme : BMWI
ID : 217090
Organisme : Argonne National Laboratory
ID : DE-AC02-06CH11357

Informations de copyright

© 2023 The Authors. Advanced Materials published by Wiley-VCH GmbH.

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Auteurs

Sarah Jasmin Finkelmeyer (SJ)

Leibniz Institute of Photonic Technology (IPHT), Albert-Einstein-Str. 9, 07745, Jena, Germany.
Institute of Physical Chemistry, Friedrich Schiller University Jena, Helmholtzweg 4, 07743, Jena, Germany.

Erik J Askins (EJ)

Department of Chemistry, University of Illinois Chicago, 845 West Taylor Street, Chicago, Illinois, 60607, USA.
Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 S. Cass Avenue, Lemont, Illinois, 60439, USA.

Jonas Eichhorn (J)

Institute of Organic Chemistry and Macromolecular Chemistry (IOMC), Friedrich-Schiller-University Jena, Humboldtstraße 10, 07743, Jena, Germany.

Soumik Ghosh (S)

Leibniz Institute of Photonic Technology (IPHT), Albert-Einstein-Str. 9, 07745, Jena, Germany.
Institute of Physical Chemistry, Friedrich Schiller University Jena, Helmholtzweg 4, 07743, Jena, Germany.
sciclus GmbH & Co. KG, Moritz-von-Rohr-Str. 1a, 07745, Jena, Germany.

Carmen Siegmund (C)

Institute for Chemistry and Biotechnology, Ilmenau University of Technology, 98684, Ilmenau, Germany.

Eric Täuscher (E)

Institute for Chemistry and Biotechnology, Ilmenau University of Technology, 98684, Ilmenau, Germany.

Andrea Dellith (A)

Leibniz Institute of Photonic Technology (IPHT), Albert-Einstein-Str. 9, 07745, Jena, Germany.

Maximilian L Hupfer (ML)

Leibniz Institute of Photonic Technology (IPHT), Albert-Einstein-Str. 9, 07745, Jena, Germany.

Jan Dellith (J)

Leibniz Institute of Photonic Technology (IPHT), Albert-Einstein-Str. 9, 07745, Jena, Germany.

Uwe Ritter (U)

Institute for Chemistry and Biotechnology, Ilmenau University of Technology, 98684, Ilmenau, Germany.

Joseph Strzalka (J)

X-Ray Science Division, Argonne National Laboratory, 9700 S. Cass Avenue, Lemont, IL, 60439, USA.

Ksenija Glusac (K)

Department of Chemistry, University of Illinois Chicago, 845 West Taylor Street, Chicago, Illinois, 60607, USA.
Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 S. Cass Avenue, Lemont, Illinois, 60439, USA.

Felix H Schacher (FH)

Institute of Organic Chemistry and Macromolecular Chemistry (IOMC), Friedrich-Schiller-University Jena, Humboldtstraße 10, 07743, Jena, Germany.
Jena Center for Soft Matter (JCSM), Friedrich-Schiller-University Jena, Philosophenweg 7, 07743, Jena, Germany.
Center for Energy and Environmental Chemistry Jena (CEEC Jena), Friedrich Schiller University Jena, Philosophenweg 7a, 07743, Jena, Germany.

Martin Presselt (M)

Leibniz Institute of Photonic Technology (IPHT), Albert-Einstein-Str. 9, 07745, Jena, Germany.
sciclus GmbH & Co. KG, Moritz-von-Rohr-Str. 1a, 07745, Jena, Germany.
Center for Energy and Environmental Chemistry Jena (CEEC Jena), Friedrich Schiller University Jena, Philosophenweg 7a, 07743, Jena, Germany.

Classifications MeSH