Structural insight into the cooperativity of spin crossover compounds.
entropy
intermolecular interactions
radiation damage
spin crossover,
thermal cyclic
Journal
Acta crystallographica Section B, Structural science, crystal engineering and materials
ISSN: 2052-5206
Titre abrégé: Acta Crystallogr B Struct Sci Cryst Eng Mater
Pays: England
ID NLM: 101609037
Informations de publication
Date de publication:
01 Oct 2023
01 Oct 2023
Historique:
received:
19
12
2022
accepted:
02
07
2023
medline:
14
8
2023
pubmed:
14
8
2023
entrez:
14
8
2023
Statut:
ppublish
Résumé
Spin-crossover (SCO) compounds are promising materials for a wide variety of industrial applications. However, the fundamental understanding of their nature of transition and its effect on the physical properties are still being fervently explored; the microscopic knowledge of their transition is essential for tailoring their properties. Here an attempt is made to correlate the changes in macroscopic physical properties with microscopic structural changes in the orthorhombic and monoclinic polymorphs of the SCO compound Fe(PM-Bia)
Identifiants
pubmed: 37578185
pii: S2052520623005814
doi: 10.1107/S2052520623005814
pmc: PMC10552598
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
354-367Informations de copyright
open access.
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