Esterification of Thioamides via Selective N-C(S) Cleavage under Mild Conditions.

Journal

Organic letters
ISSN: 1523-7052
Titre abrégé: Org Lett
Pays: United States
ID NLM: 100890393

Informations de publication

Date de publication:
25 Aug 2023
Historique:
medline: 14 8 2023
pubmed: 14 8 2023
entrez: 14 8 2023
Statut: ppublish

Résumé

Herein, we report an exceedingly mild method for the direct, transition-metal-free esterification of thioamides through the selective generation of tetrahedral intermediates. The method represents the first transition-metal-free approach to the thioamide to thionoester transformation in organic synthesis. This reactivity has been accomplished through

Identifiants

DOI: 10.1021/acs.orglett.3c02238 PMID: 37578346
pubmed: 37578346
doi: 10.1021/acs.orglett.3c02238
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

6149-6154

Auteurs

Xinhao Zhu (X)

College of Chemistry and Chemical Engineering, Key Laboratory of Chemical Additives for China National Light Industry, Shaanxi University of Science and Technology, Xi'an 710021, China.

Kerou Wan (K)

Shaanxi Key Laboratory of Catalytic Materials and Technology, Kaili Catalyst & New Materials Company, Ltf., Xi'an 710299, China.

Jin Zhang (J)

College of Chemistry and Chemical Engineering, Key Laboratory of Chemical Additives for China National Light Industry, Shaanxi University of Science and Technology, Xi'an 710021, China.
ORCID: 0000-0002-6616-7087

Hui Zhao (H)

College of Chemistry and Chemical Engineering, Key Laboratory of Chemical Additives for China National Light Industry, Shaanxi University of Science and Technology, Xi'an 710021, China.

Yang He (Y)

College of Chemistry and Chemical Engineering, Key Laboratory of Chemical Additives for China National Light Industry, Shaanxi University of Science and Technology, Xi'an 710021, China.

Yangmin Ma (Y)

College of Chemistry and Chemical Engineering, Key Laboratory of Chemical Additives for China National Light Industry, Shaanxi University of Science and Technology, Xi'an 710021, China.

Xiufang Yang (X)

College of Chemistry and Chemical Engineering, Key Laboratory of Chemical Additives for China National Light Industry, Shaanxi University of Science and Technology, Xi'an 710021, China.

Michal Szostak (M)

Department of Chemistry, Rutgers University, 73 Warren Street, Newark, New Jersey 07102, United States.
ORCID: 0000-0002-9650-9690

Classifications MeSH