There is plenty of asbestos at the bottom. The case of magnesite raw material contaminated with asbestos fibres.

Asbestos Chrysotile Electron microscopy Magnesite REACH Rotterdam Convention

Journal

The Science of the total environment
ISSN: 1879-1026
Titre abrégé: Sci Total Environ
Pays: Netherlands
ID NLM: 0330500

Informations de publication

Date de publication:
10 Nov 2023
Historique:
received: 22 04 2023
revised: 14 07 2023
accepted: 11 08 2023
medline: 16 8 2023
pubmed: 16 8 2023
entrez: 15 8 2023
Statut: ppublish

Résumé

Although all six asbestos minerals (the layer silicate chrysotile and five chain silicate species actinolite asbestos, amosite, anthophyllite asbestos, crocidolite and tremolite asbestos) are classified as carcinogenic, chrysotile is still mined and used in many countries worldwide. Other countries, like Italy, impose zero tolerance for all asbestos species, but conflicting views repress the development of globally uniform treaties controlling international trade of asbestos-containing materials. Hence, countries with more severe legislations against the use of these hazardous materials lack of an international safety net against importation of non-compliant products. This research reports the first discovery of commercial magnesite raw materials contaminated with white asbestos (chrysotile). X-ray powder diffraction and thermogravimetric/thermodifferential measurements showed the presence of serpentine group minerals in both the semi-processed (powder) and quarried material. The univocal identification of chrysotile in the powders was confirmed by its peculiar Raman bands of the OH stretching vibrations between 3500 and 3800 cm

Identifiants

pubmed: 37582451
pii: S0048-9697(23)04900-8
doi: 10.1016/j.scitotenv.2023.166275
pii:
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

166275

Informations de copyright

Copyright © 2023 Elsevier B.V. All rights reserved.

Déclaration de conflit d'intérêts

Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. The authors wish to state that the commercial samples analysed in this study were provided by Italian suppliers and end-users and considered representative of batches present in the manufacture sites in Italy during the autumn period of the year 2021. Evidence of asbestos contamination from this work is intended only for the analysed samples and, in the absence of further experimental data, should be regarded as accidental. Under no circumstances should the results of this study be generalized in space and time and considered valid for other commercial magnesite samples.

Auteurs

Alessandro F Gualtieri (AF)

Department of Chemical and Geological Sciences, University of Modena and Reggio Emilia, Via G. Campi 103, 41125 Modena, Italy; Inter-Departmental Research and Innovation Centre on Construction and Environmental Services of the University of Modena and Reggio Emilia, Italy.

Daniele Malferrari (D)

Department of Chemical and Geological Sciences, University of Modena and Reggio Emilia, Via G. Campi 103, 41125 Modena, Italy; Inter-Departmental Research and Innovation Centre on Construction and Environmental Services of the University of Modena and Reggio Emilia, Italy. Electronic address: daniele.malferrari@unimore.it.

Dario Di Giuseppe (D)

Department of Chemical and Geological Sciences, University of Modena and Reggio Emilia, Via G. Campi 103, 41125 Modena, Italy.

Valentina Scognamiglio (V)

Department of Chemical and Geological Sciences, University of Modena and Reggio Emilia, Via G. Campi 103, 41125 Modena, Italy.

Orietta Sala (O)

Department of Chemical and Geological Sciences, University of Modena and Reggio Emilia, Via G. Campi 103, 41125 Modena, Italy.

Magdalena Lassinantti Gualtieri (ML)

Department of Engineering "Enzo Ferrari", University of Modena and Reggio Emilia, Via Vivarelli 10, 41125 Modena, Italy.

Danilo Bersani (D)

Department of Mathematical, Physical and Computer Sciences, University of Parma, Parco Area delle Scienze 7/A, 43124 Parma, Italy.

Laura Fornasini (L)

Department of Mathematical, Physical and Computer Sciences, University of Parma, Parco Area delle Scienze 7/A, 43124 Parma, Italy.

Enrico Mugnaioli (E)

Department of Earth Sciences, University of Pisa, Via Santa Maria 53, 56126 Pisa, Italy.

Classifications MeSH