Aluminium and Gallium Silylimides as Nitride Sources.
aluminium
carbon monoxide
gallium
imide
metathesis
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
24 Nov 2023
24 Nov 2023
Historique:
received:
02
08
2023
medline:
22
8
2023
pubmed:
22
8
2023
entrez:
21
8
2023
Statut:
ppublish
Résumé
Terminal aluminium and gallium imides of the type K[(NON)M(NR)], bearing heteroatom substituents at R, have been synthesised via reactions of anionic aluminium(I) and gallium(I) reagents with silyl and boryl azides (NON=4,5-bis(2,6-diisopropyl-anilido)-2,7-di-tert-butyl-9,9-dimethyl-xanthene). These systems vary significantly in their lability in solution: the N(Si
Identifiants
pubmed: 37604785
doi: 10.1002/chem.202302512
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202302512Subventions
Organisme : Leverhulme Trust
ID : RP-2018-246
Informations de copyright
© 2023 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH.
Références
D. J. Grant, D. A. Dixon, J. Phys. Chem. A 2005, 109, 10138-10147.
H. W. Langmi, G. S. McGrady, Coord. Chem. Rev. 2007, 251, 925-935.
T. B. Marder, Angew. Chem. Int. Ed. 2007, 46, 8116-8118.
J. A. Jegier, W. L. Gladfelter, Coord. Chem. Rev. 2000, 206-207, 631-650.
For an early example, see: A. W. Laubengayer, J. D. Smith, G. G. Ehrlich, J. Am. Chem. Soc. 1961, 83, 542-546.
M. Veith, Chem. Rev. 1990, 90, 3-16;
S. J. Schauer, G. H. Robinso, J. Coord. Chem. 1993, 30, 197-214;
A. Y. Timoshkin, Coord. Chem. Rev. 2005, 249, 2094-213;
C. J. Carmalt, Coord. Chem. Rev. 2001, 223, 217-264;
P. J. Brothers, P. P. Power, Adv. Organomet. Chem. 1996, 39, 1-69;
S. Aldridge in The Group 13 Metals Aluminium, Gallium, Indium and Thallium: Chemical Patterns and Peculiarities (Eds.: A. J. Downs, S. Aldridge), Wiley, Chichester, 2011, pp122-132.
K. M. Waggoner, P. P. Power, J. Am. Chem. Soc. 1991, 113, 3385-3393.
R. J. Wehmschulte, P. P. Power, J. Am. Chem. Soc. 1996, 118, 791-796.
M. Cesari, G. Perego, G. del Piero, S. Cucinella, E. Cernia, J. Organomet. Chem. 1974, 78, 203-213.
G. del Piero, M. Cesari, G. Dossi, A. Mazzei, J. Organomet. Chem. 1977, 129, 281-288.
G. del Piero, M. Cesari, G. Perego, S. Cucinella, E. Cernia, J. Organomet. Chem. 1977, 129, 289-298.
T. Belgardt, S. D. Waezsada, H. W. Roesky, H. Gornitzka, L. Häming, D. Stalke, Inorg. Chem. 1994, 33, 6247-6251.
N. D. Reddy, H. W. Roesky, M. Noltemeyer, H. G. Schmidt, Inorg. Chem. 2002, 41, 2374-2378.
K. M. Waggoner, H. Hope, P. P. Power, Angew. Chem. Int. Ed. 1988, 27, 1699-1700.
S. Schulz, A. Voigt, H. W. Roesky, L. Häming, R. Herbst-Irmer, Organometallics 1996, 15, 5252-5253.
S. Schulz, L. Häming, R. Herbst-Irmer, H. W. Roesky, G. M. Sheldrick, Angew. Chem. Int. Ed. 1994, 33, 969-970.
J. D. Fisher, P. J. Shapiro, G. P. A. Yap, A. L. Rheingold, Inorg. Chem. 1996, 35, 271-272.
S. Schulz, F. Thomas, W. M. Priesmann, M. Nieger, Organometallics 2006, 25, 1392-1398.
A. Hofmann, T. Tröster, T. Kupfer, H. Braunschweig, Chem. Sci. 2019, 10, 3421-3428.
H. Zhu, J. Chai, V. Chandrasekhar, H. W. Roesky, J. Magull, D. Vidovic, H. G. Schmidt, M. Noltemeyer, P. P. Power, W. A. Merrill, J. Am. Chem. Soc. 2004, 126, 9472-9473.
M. D. Anker, M. Lein, M. P. Coles, Chem. Sci. 2019, 10, 1212-1218.
H. Zhu, Z. Yang, J. Magull, H. W. Roesky, H. G. Schmidt, M. Noltemeyer, Organometallics 2005, 24, 6420-6425.
C. Cui, H. W. Roesky, H.-G. Schmidt, M. Noltemeyer, Angew. Chem. Int. Ed. 2000, 39, 4531-4533.
M. D. Anker, Y. Altaf, M. Lein, M. P. Coles, Dalton Trans. 2019, 48, 16588-16594.
N. J. Hardman, P. P. Power, Chem. Commun. 2001, 1, 1184-1185.
Q. Yu, L. Zhang, Y. He, J. Pan, H. Li, G. Bian, X. Chen, G. Tan, Chem. Commun. 2021, 57, 9268-9271.
J. D. Queen, S. Irvankoski, J. C. Fettinger, H. M. Tuononen, P. P. Power, J. Am. Chem. Soc. 2021, 143, 6351-6356.
J. Li, X. Li, W. Huang, H. Hu, J. Zhang, C. Cui, Chem. Eur. J. 2012, 18, 15263-15266.
N. J. Hardman, C. Cui, H. W. Roesky, W. H. Fink, P. P. Power, Angew. Chem. Int. Ed. 2001, 40, 2172-2174.
R. J. Wright, M. Brynda, J. C. Fettinger, A. R. Betzer, P. P. Power, J. Am. Chem. Soc. 2006, 128, 12498-12509.
R. J. Wright, A. D. Phillips, T. L. Allen, W. H. Fink, P. P. Power, J. Am. Chem. Soc. 2003, 125, 1694-1695.
M. D. Anker, R. J. Schwamm, M. P. Coles, Chem. Commun. 2020, 56, 2288-2291.
A. Heilmann, J. Hicks, P. Vasko, J. M. Goicoechea, S. Aldridge, Angew. Chem. Int. Ed. 2020, 59, 4897-4901;
A. Heilmann, P. Vasko, J. Hicks, J. M. Goicoechea, S. Aldridge, Chem. Eur. J. 2023, 29, e202300018.
For related chalcogenide chemistry, see for example:
J. Hicks, A. Heilmann, P. Vasko, J. M. Goicoechea, S. Aldridge, Angew. Chem. Int. Ed. 2019, 58, 17265-17268;
M. D. Anker, M. P. Coles, Angew. Chem. Int. Ed. 2019, 58, 18261-18265;
M. J. Evans, M. D. Anker, C. L. McMullin, N. A. Rajabi, M. P. Coles, Chem. Commun. 2021, 57, 2673-2676;
M. J. Evans, M. D. Anker, C. L. McMullin, S. E. Neale, N. A. Rajabi, M. P. Coles, Chem. Sci. 2022, 13, 4635-4646.
J. Hicks, P. Vasko, J. M. Goicoechea, S. Aldridge, Nature 2018, 557, 92-95.
For quantum chemical discussions of π-bonding in related systems see, for example:
A. Y. Timoshkin, H. F. Schaefer, J. Phys. Chem. A 2008, 112, 13180-13196;
S. L. Zhang, M. C. Yang, M. der Su, RSC Adv. 2019, 9, 12195-12208.
B. Cordero, V. Gómez, A. E. Platero-Prats, M. Revés, J. Echeverría, E. Cremades, F. Barragán, S. Alvarez, Dalton Trans. 2008, 2832-2838.
M. Xu, Z. W. Qu, S. Grimme, D. W. Stephan, J. Am. Chem. Soc. 2021, 143, 634-638.
M. Xu, B. Kooij, T. Wang, J. H. Lin, Z. W. Qu, S. Grimme, D. W. Stephan, Angew. Chem. Int. Ed. 2021, 60, 16965-16969.
The reactivity of a molecular aluminium oxide towards CO has also been reported: M. D. Anker, C. L. McMullin, N. A. Rajabi, M. P. Coles, Angew. Chem. Int. Ed. 2020, 59, 12806-12810.
M. J. Evans, M. D. Anker, C. L. McMullin, M. P. Coles, Chem. Sci. 2023, 14, 6278-6288.
A. Kempter, C. Gemel, R. A. Fischer, Chem. Eur. J. 2007, 13, 2990-3000.
A. W. Addison, N. T. Rao, J. Reedijk, J. van Rijn, G. C. Verschoor, J. Chem. Soc. Dalton Trans. 1984, 1349-1356.
K. Nakamoto The Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part B: Applications in Coordination, Organometallic and Bioinorganic Chemistry 6th edn., Wiley, Hoboken, 2009, pp120-132.
See, for example: N. Del Rio, A. Baceiredo, N. Saffon-Merceron, D. Hashizume, D. Lutters, T. Müller, T. Kato, Angew. Chem. Int. Ed. 2016, 55, 4753-4758.
Deposition Numbers 2285008-2285015 (for K[1]-K2[6]2) contain the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum Karlsruhe Access Structures service.
Y. Itagaki, T. Iseoka, T. Iida, J. Ohshita, M. Shiotani, A. Kunai, Chem. Phys. Lett. 2001, 348, 249-254;
H. Braunschweig, M. A. Celik, T. Dellermann, G. Frenking, K. Hammond, F. Hupp, H. Kelch, I. Krummenacher, F. Lindl, L. Mailänder, J. H. Müssig, A. Ruppert, Chem. Eur. J. 2017, 23, 8006-8013.
J. Cosier, A. M. Glazer, J. Appl. Crystallogr. 1986, 19, 105-107.
CrysAlisPro, Agilent Technologies, Yarnton, UK, Version 1.171.35.8.
G. M. Sheldrick, Acta Crystallogr. Sect. A 2015, 71, 3-8.
G. M. Sheldrick, Acta Crystallogr. Sect. C 2015, 71, 3-8.
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard, H. Puschmann, J. Appl. Crystallogr. 2009, 42, 339-341.
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard, H. Puschmann, J. Appl. Crystallogr. 2009, 42, 339-341;
F. Neese, Wiley Interdiscip. Rev.: Comput. Mol. Sci. 2012, 2, 73-78.
S. Grimme, A. Hansen, S. Ehlert, J.-M. Mewes, J. Chem. Phys. 2021, 154, 064103.
E. D. Glendening, J. K. Badenhoop, A. E. Reed, J. E. Carpenter, J. A. Bohman, C. M. Morales, P. Karafiloglou, C. R. Landis, F. Weinhold, NBO 7.0 2018.
M. P. Mitoraj, M. Parafiniuk, M. Srebro, M. Handzlik, A. Buczek, A. Michalak, J. Mol. Model. 2011, 17, 2337-2352.