Application of Polymer-Embedded Tetrabutylammonium Bromide (TBAB) Membranes for the Selective Extraction of Metal Ions from Aqueous Solutions.

The selective extraction of metals from aqueous solutions is a very important stage in the hydrometallurgical processing of metallic waste. Leach solutions are usually a multicomponent mixture. The main impurity of aqueous solutions obtained after leaching using inorganic acids is iron. In this work, the membrane separation of iron(III) from nickel(II), cobalt(II), and lithium(I) was studied. The facilitated transport of metal ions using polymer inclusion membranes (PIMs) with tetrabutylammonium bromide (TBAB) as an ion carrier under various conditions was analyzed in detail. Several factors, such as the ion carrier concentration in the membrane as well as the effect of the inorganic acid concentration in the source/receiving phases on the kinetic parameters, were investigated. The results show that ionic liquid TBAB is a very selective ion carrier of Fe(III) towards Ni(II), Co(II), and Li(I).