Weakly Self-Assembled [6]Helicenes: Circularly Polarized Light and Spin Filtering Properties.
chiral induced spin selectivity
circularly polarized luminescence
helicenes
spin polarization
supramolecular assemblies
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
13 Nov 2023
13 Nov 2023
Historique:
received:
14
07
2023
medline:
28
8
2023
pubmed:
28
8
2023
entrez:
27
8
2023
Statut:
ppublish
Résumé
Self-assembling features, chiroptical activity, and spin filtering properties are reported for 2,15- and 4,13-disubstituted [6]helicenes decorated in their periphery with 3,4,5-tris(dodecyloxy)-N-(4-ethynylphenyl)benzamide moieties. The weak non-covalent interaction between these units conditions the corresponding circularly polarized luminescence and spin polarization. The self-assembly is overall weak for these [6]helicene derivatives that, despite the formation of H-bonding interactions between the amide groups present in the peripheral moieties, shows very similar chiroptical properties both in the monomeric or aggregated states. This effect could be explained by considering the steric effect that these groups could generate in the growing of the corresponding aggregate formed. Importantly, the self-assembling features also condition chiral induced spin selectivity (CISS effect), with experimental spin polarization (SP) values found between 35-40 % for both systems, as measured by magnetic-conducting atomic force microscopy (AFM) technique.
Identifiants
pubmed: 37635073
doi: 10.1002/chem.202302254
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202302254Subventions
Organisme : Ministerio de Ciencia e Innovación
ID : PID2020-113512GB-I00
Organisme : Ministerio de Ciencia e Innovación
ID : TED2021-130285B-I00
Organisme : Xunta de Galicia
Organisme : Israeli Ministry for Science and Technology
Organisme : H2020 European Research Council
ID : 859752
Informations de copyright
© 2023 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH.
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