Attenuation of wind intensities exacerbates anoxic conditions leading to sulfur plume development off the coast of Peru.


Journal

PloS one
ISSN: 1932-6203
Titre abrégé: PLoS One
Pays: United States
ID NLM: 101285081

Informations de publication

Date de publication:
2023
Historique:
received: 24 05 2022
accepted: 15 06 2023
medline: 1 9 2023
pubmed: 30 8 2023
entrez: 30 8 2023
Statut: epublish

Résumé

The release of vast quantities of sulfide from the sediment into the water column, known as a sulfidic event, has detrimental consequences on fish catches, including downstream effects on other linked element cycles. Despite being frequent occurrences in marine upwelling regions, our understanding of the factors that moderate sulfidic event formation and termination are still rudimentary. Here, we examined the biogeochemical and hydrodynamic conditions that underpinned the formation/termination of one of the largest sulfur plumes to be reported in the Peruvian upwelling zone. Consistent with previous research, we find that the sulfur-rich plume arose during the austral summer when anoxic conditions (i.e., oxygen and nitrate depletion) prevailed in waters overlying the upper shelf. Furthermore, the shelf sediments were organically charged and characterized by low iron-bound sulfur concentrations, further enabling the diffusion of benthic-generated sulfide into the water column. While these biogeochemical conditions provided a predicate to sulfidic event formation, we highlight that attenuations in local wind intensity served as an event trigger. Namely, interruptions in local wind speed constrained upwelling intensity, causing increased stratification over the upper shelf. Moreover, disturbances in local wind patterns likely placed additional constraints on wind-driven mesoscale eddy propagation, with feedback effects on coastal elemental sulfur plume (ESP) formation. We suggest ESP development occurs as a result of a complex interaction of biogeochemistry with regional hydrodynamics.

Identifiants

pubmed: 37647254
doi: 10.1371/journal.pone.0287914
pii: PONE-D-22-14284
pmc: PMC10468053
doi:

Substances chimiques

Sulfur 70FD1KFU70
Sulfides 0
Water 059QF0KO0R

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

e0287914

Informations de copyright

Copyright: © 2023 Flores et al. This is an open access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.

Déclaration de conflit d'intérêts

The authors have declared that no competing interests exist.

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Auteurs

Edgart Flores (E)

Programa de Maestría de Ciencias del Mar, Universidad Peruana Cayetano Heredia, Lima, Peru.
Millennium Institute of Oceanography, Universidad de Concepción, Concepción, Chile.
Department of Geological Sciences, Institute of Arctic and Alpine Research, University of Colorado, Boulder, Colorado, United States of America.

Ursula Mendoza (U)

Dirección General de Investigaciones en Oceanografía y Cambio Climático, Instituto del Mar del Perú, Callao, Peru.
Facultad de Ciencias Veterinarias y Biológicas, Escuela de Biología Marina, Universidad Científica del Sur, Lima, Peru.

Cameron M Callbeck (CM)

Department of Environmental Sciences, University of Basel, Basel, Switzerland.

Rut Díaz (R)

Programa de Geoquímica, Universidade Federal Fluminense, Niterói, Rio de Janeiro, Brazil.

Arturo Aguirre-Velarde (A)

Dirección General de Investigaciones en Acuicultura, Instituto del Mar del Perú, Callao, Peru.

Michael E Böttcher (ME)

Geochemistry & Isotope Biogeochemistry Group, Department of Marine Geology, Leibniz Institute for Baltic Sea Research, Warnemünde, Germany.
Marine Geochemistry, University of Greifswald, Greifswald, Germany.
Interdisciplinary Faculty, University of Rostock, Rostock, Germany.

Lander Merma-Mora (L)

Programa de Maestría de Ciencias del Mar, Universidad Peruana Cayetano Heredia, Lima, Peru.

Manuel Moreira (M)

Programa de Geoquímica, Universidade Federal Fluminense, Niterói, Rio de Janeiro, Brazil.

Maritza S Saldarriaga (MS)

Dirección General de Investigaciones de Recursos Demersales y Litorales, Instituto del Mar del Perú, Callao, Peru.

Emmanoel V Silva-Filho (EV)

Programa de Geoquímica, Universidade Federal Fluminense, Niterói, Rio de Janeiro, Brazil.

Ana L Albuquerque (AL)

Departamento de Geologia e Geofísica, Universidade Federal Fluminense, Niterói, Rio de Janeiro, Brazil.

Matias Pizarro-Koch (M)

Escuela de Ingeniería Civil Oceánica, Facultad de Ingeniería, Universidad de Valparaíso, Valparaíso, Chile.
Millennium Nucleus Understanding Past Coastal Upwelling Systems and Environmental Local and Lasting Impacts, Coquimbo, Chile.

Michelle Graco (M)

Programa de Maestría de Ciencias del Mar, Universidad Peruana Cayetano Heredia, Lima, Peru.
Dirección General de Investigaciones en Oceanografía y Cambio Climático, Instituto del Mar del Perú, Callao, Peru.

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Classifications MeSH