Plasmonic Dodecahedral-Walled Elongated Nanoframes for Surface-Enhanced Raman Spectroscopy.
hot spots
nanoframes
nanorods
plasmonics
surface-enhanced Raman spectroscopy (SERS)
Journal
Small (Weinheim an der Bergstrasse, Germany)
ISSN: 1613-6829
Titre abrégé: Small
Pays: Germany
ID NLM: 101235338
Informations de publication
Date de publication:
08 Sep 2023
08 Sep 2023
Historique:
revised:
14
07
2023
received:
31
05
2023
medline:
9
9
2023
pubmed:
9
9
2023
entrez:
9
9
2023
Statut:
aheadofprint
Résumé
Here, elongated pseudohollow nanoframes composed of four rectangular plates enclosing the sides and two open-frame ends with four ridges pointing at the tips for near-field focusing are reported. The side facets act as light-collecting domains and transfer the collected light to the sharp tips for near-field focusing. The nanoframes are hollow inside, allowing the gaseous analyte to penetrate through the entire architecture and enabling efficient detection of gaseous analytes when combined with Raman spectroscopy. The resulting nanostructures are named Au dodecahedral-walled nanoframes. Synthesis of the nanoframes involves shape transformation of Au nanorods with round tips to produce Au-elongated dodecahedra, followed by facet-selective Pt growth, etching of the inner Au, and regrowth steps. The close-packed assembly of Au dodecahedral-walled nanoframes exhibits an attomolar limit of detection toward benzenethiol. This significant enhancement in SERS is attributed to the presence of a flat solid terrace for a large surface area, sharp edges and vertices for strong electromagnetic near-field collection, and open frames for effective analyte transport and capture. Moreover, nanoframes are applied to detect chemical warfare agents, specifically mustard gas simulants, and 20 times higher sensitivity is achieved compared to their solid counterparts.
Identifiants
pubmed: 37688300
doi: 10.1002/smll.202304567
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2304567Subventions
Organisme : Department of Chemistry, Sungkyunkwan University
Organisme : National Research Foundation of Korea (NRF)
Organisme : Korea government (MSIT)
ID : NRF-2022R1A2C2002869
Organisme : Korea government (MSIT)
ID : NRF-2022R1C1C2003784
Organisme : challengeable Future Defense Technology Research and Development Program
Organisme : Defense Acquisition Program Administration (DAPA)
ID : 915019201
Informations de copyright
© 2023 Wiley-VCH GmbH.
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