Phosphorus doped cyanobacterial biochar catalyzes efficient persulfate oxidation of the antibiotic norfloxacin.
Antibiotic
Degradation kinetics
EPR
Environmental catalysis
Phosphorus doping
Journal
Bioresource technology
ISSN: 1873-2976
Titre abrégé: Bioresour Technol
Pays: England
ID NLM: 9889523
Informations de publication
Date de publication:
Nov 2023
Nov 2023
Historique:
received:
17
07
2023
revised:
05
09
2023
accepted:
12
09
2023
medline:
11
10
2023
pubmed:
19
9
2023
entrez:
18
9
2023
Statut:
ppublish
Résumé
In this study, cyanobacterial biochars (CBs) enriched/doped with non-metallic elements were prepared by pyrolysis of biomass amended with different N, S, and P containing compounds. Their catalytic reactivity was tested for persulfate oxidation of the antibiotic norfloxacin (NOR). N and S doping failed to improve CB catalytic reactivity, while P doping increased reactivity 5 times compared with un-doped biochar. Biochars produced with organic phosphorus dopants showed the highest reactivity. Post-acid-washing improved catalytic reactivity. In particular, 950 ℃ acid-washed triphenyl-phosphate doped CB showed the largest degradation rate and reached 79% NOR mineralization in 2 h. Main attributes for P-doped CBs high reactivity were large specific surface areas (up to 655 m
Identifiants
pubmed: 37722544
pii: S0960-8524(23)01213-0
doi: 10.1016/j.biortech.2023.129785
pii:
doi:
Substances chimiques
biochar
0
Anti-Bacterial Agents
0
Norfloxacin
N0F8P22L1P
Phosphorus
27YLU75U4W
Charcoal
16291-96-6
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
129785Informations de copyright
Copyright © 2023 The Author(s). Published by Elsevier Ltd.. All rights reserved.
Déclaration de conflit d'intérêts
Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.